Results 311 to 320 of about 3,257,828 (382)

Recent Advances in Variable‐Stiffness Robotic Systems Enabled by Phase‐Change Materials

open access: yesAdvanced Robotics Research, EarlyView.
Phase‐change materials (PCMs), such as shape memory alloys, hydrogels, shape memory polymers, liquid crystal elastomers, and low‐melting‐point alloys, are driving advancements in stiffness‐tunable robotic systems across a wide range of applications. This review highlights recent progress in PCM‐enabled robotics, focusing on their underlying mechanisms,
Sukrit Gaira   +5 more
wiley   +1 more source

Rhodium‐Catalyzed Oxidative CH o‐Arylation of s‐Aryltetrazines with Aryl Boronic Acids: One‐Step Selective Access to T‐Shaped and Z‐Shaped Polyaromatics

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A one‐step regioselective access to T‐Shaped and Z‐Shaped polyaromatics s‐tetrazines by a rhodium‐catalyzed oxidative CH o‐functionalization is reported. Electron‐rich aryl coupling partners display a higher reactivity than electron‐poor aryl, and allow the formation of poly(hetero)aromatic derivatives while avoiding 1,4‐azaphilic addition of the ...
Oumaima Abidi   +6 more
wiley   +1 more source

Azabicyclo[1.1.0]butyl‐Substituted Sulfonimidoyl Fluoride: Electrophilic Hub Bridging Late‐Stage Azetidine Incorporation with Sufex Chemistry

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
GA: Strained small motifs and SuFEx hubs are of increasing importance in drug discovery to enable efficient late‐stage functionalization. Here, the synthesis of bench‐stable azabicyclo[1.1.0]butyl‐substituted sulfonimidoyl fluoride as an electrophilic hub with dual activation mode is reported.
Defne Serbetci   +5 more
wiley   +1 more source

Solvent‐Free Mechanocatalytic Reduction of Nitro Compounds with Hydrogen Gas and its Application in the Synthesis of Drugs and their Intermediates

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A solvent‐free mechanochemical reduction of nitro compounds using hydrogen gas is presented. In addition to enabling the synthesis of a variety of functionalized aniline derivatives, the method has been scaled up to gram quantities, evaluated for trace metal impurities, and applied to the synthesis of pharmaceutical compounds and their precursors.
Samarth Bhatnagar   +2 more
wiley   +1 more source

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