Results 61 to 70 of about 6,399 (235)

Speciation‐Controlled C–F Bond Functionalization Enabled by Zwitterionic Pnictinidenes

Angewandte Chemie, EarlyView.
Zwitterionic pnictinidenes turn C–F activation into C–X bond construction, enabling broad defluorinative functionalization of polyfluoro(hetero)arenes under mild conditions. Rather than following a metallomimetic Sb(I)/Sb(III) redox turnover, catalysis is redirected by ligand scrambling into a redox‐neutral manifold, revealing catalyst speciation as a ...
Irene Sánchez‐Sordo, Sergio Fernandez, Selwin Fernando, Diego M. Andrada, Oriol Planas   +4 more
wiley   +2 more sources

Effects of Plasma Power on By-Product Gas Formation from CHF₃ and CH₂F₂ Process Gases in Semiconductor Etching Processes

Applied Sciences
In semiconductor manufacturing, fluorinated gases such as CHF3 and CH2F2 are widely used as process gases for plasma etching and cleaning. However, their decomposition within the plasma environment leads to the formation of secondary fluorinated by ...
Dae Kee Min, Jiyun Woo, Joohee Lee, Bong-Jae Lee, Eui-chan Jeon   +4 more
doaj   +1 more source

Recent Advances in Plasma‐Enhanced Atomic Layer Etching for Next‐Generation Nanofabrication

Advanced Materials Interfaces, EarlyView.
Continued semiconductor miniaturization demands atomic‐scale patterning and ultralow surface roughness beyond the capabilities of conventional reactive ion etching. This review highlights advances in isotropic and anisotropic plasma‐enhanced atomic layer etching since 2020, covering fundamental mechanisms, applications across major semiconductor ...
Shih‐Nan Hsiao
wiley   +1 more source

Fluorocarbons

Journal of the Franklin Institute, 1958
Mode of access: Internet.
openaire   +2 more sources

3D Liquid Crystal Framework Enclosing Dual Compartments

Angewandte Chemie, EarlyView.
A new type of liquid crystal phase is reported, having the conjugated rod‐like molecular cores form a 3D framework of elongated octahedral cages filled alternatively with alkyl and fluoroalkyl pendant chains. The cages are held together by flexible H‐bonding hinges, making them adaptable to thermal expansion and stable in a wide temperature range.
Yang‐yang Zhao, Huan‐jun Lu, Helgard Ebert, Xiang‐bing Zeng, Chunlan Ma, Feng Liu, Carsten Tschierske, Goran Ungar   +7 more
wiley   +2 more sources

Turning Water Into a Tool: From Degradation Pathways to Functional Engineering in Halide Perovskites

Advanced Materials Technologies, EarlyView.
Water exhibits a threshold‐dependent dual role in lead halide perovskites, acting either as a degradation trigger or as a powerful tool for defect passivation, recrystallization, and structural engineering. This review discusses how controlled water‐mediated interactions govern stability, dimensionality, and optoelectronic performance, providing ...
Raphaella T. S. Gonçalves, Gabriela O. Gera, Aryane Tofanello, Jose A. Souza, Andre L. M. Freitas   +4 more
wiley   +1 more source

Microfabrication of Soft Millirobots Propelled by Low Voltage Electrohydraulic Actuators

Advanced Materials Technologies, EarlyView.
Manual layer‐by‐layer assembly is replaced by wafer‐level MEMS batch fabrication for compliant polymer‐based electrohydraulic actuators. The microfabricated devices integrate sacrificially defined microcavities, Parylene‐C‐sealed inlets, and multilayer polymer–metal films.
Shai Shmulevich, Florian Hartmann, Herbert Shea   +2 more
wiley   +1 more source

Official health communications are failing PFAS-contaminated communities

Environmental Health, 2022
Background Environmental health agencies are critical sources of information for communities affected by chemical contamination. Impacted residents and their healthcare providers often turn to federal and state agency webpages, fact sheets, and other ...
Alan Ducatman, Jonas LaPier, Rebecca Fuoco, Jamie C. DeWitt   +3 more
doaj   +1 more source

ML Workflows for Screening Degradation‐Relevant Properties of Forever Chemicals

Advanced Science, EarlyView.
The environmental persistence of per‐ and polyfluoroalkyl substances (PFAS) necessitates efficient remediation strategies. This study presents physics‐informed machine learning workflows that accurately predict critical degradation properties, including bond dissociation energies and polarizability.
Pranoy Ray, Andrew R. Castillo, Manoj Kolel‐Veetil, Surya R. Kalidindi   +3 more
wiley   +1 more source

Curvature‐Controlled Field Effect Enables Thermal Localization for Low‐Temperature C─F Bond Activation

Advanced Science, EarlyView.
High‐curvature γ‐Al2O3 nanoneedles concentrate heat into nanoscale hotspots under identical external heating, amplifying local temperature and accelerating CF4 decomposition. By linking curvature‐induced thermal localization to lower apparent activation barriers and enhanced intermediate formation, this work reveals geometry as a powerful design ...
Hang Zhang, Jialin Zheng, Xiaojian Wang, Hao Yu, Diya Xie, Wenjie Luo, Minghui Yang, Kang Liu, Yuxia Duan, Zhang Lin, Liyuan Chai, Emiliano Cortés, Min Liu   +12 more
wiley   +1 more source