Results 81 to 90 of about 786,969 (117)

f‐p‐d Gradient Orbital Coupling Induced Spin State Enhancement of Atomic Fe Sites for Efficient and Stable Oxygen Reduction Reaction

Advanced Functional Materials, EarlyView.
The f‐p‐d (Eu─O─Fe) gradient orbital coupling induces electron delocalization and the introduced f‐band of Eu shifts the spin state of the Fe center in FePc from low‐spin to intermediate‐spin. This strategy simultaneously enhances oxygen reduction reaction (ORR) activity, reaction kinetics, and stability, resulting in superior ORR performance and ...
Ruiqi Cheng, Xiaoqian He, Min Jiang, Xichen Shao, Wenqi Tang, Biao Ran, Huanxin Li, Chaopeng Fu   +7 more
wiley   +1 more source

Engineering a Spin‐Orbit Bandgap in Graphene‐Tellurium Heterostructures

Advanced Functional Materials, EarlyView.
Tellurium intercalation in epitaxial graphene on Ir(111) enables the emergence of a spin–orbit‐induced bandgap with energy spin splitting. By combining STM, ARPES, spin‐resolved ARPES, and DFT, two structural phases are identified, both exhibiting tunable electronic doping.
Beatriz Muñiz Cano, Fabián Calleja, Daniela Pacilè, Marc G. Cuxart, Michele Pisarra, Antonello Sindona, Fernando Martín, Elena Salagre, Pilar Segovia, Enrique G. Michel, Amadeo. L. Vázquez de Parga, Rodolfo Miranda, Julio Camarero, Manuela Garnica, Miguel Angel Valbuena   +14 more
wiley   +1 more source

Biodegradable, Humidity‐Insensitive Mask‐Integrated E‐Nose for Sustainable and Non‐Invasive Continuous Breath Analysis

Advanced Functional Materials, EarlyView.
This study introduces a paper‐based biodegradable, humidity‐insensitive e‐nose for real‐time breath analysis, addressing challenges in existing technologies such as humidity interference, high costs, and environmental impact. Featuring hydrophobic polymer coatings, these sensors reliably detect VOCs even in high‐moisture environments.
Indrajit Mondal, Adan Zoabi, Hossam Haick   +2 more
wiley   +1 more source

Oxygen Defect Engineering of Hexagonal Perovskite Oxides to Boost Catalytic Performance for Aerobic Oxidation of Sulfides to Sulfones

Advanced Functional Materials, EarlyView.
Ru‐substituted hexagonal perovskite SrMnO3, featuring face‐shared oxygen species, is designed as an effective heterogeneous catalyst for the aerobic oxidation of sulfides. The catalyst demonstrates high selectivity to sulfones (>99%) under mild reaction conditions (≥30 °C). Ru substitution promotes oxygen vacancy formation of face‐shared oxygen species
Keiju Wachi, Masashi Makizawa, Takeshi Aihara, Shin Kiyohara, Yu Kumagai, Keigo Kamata   +5 more
wiley   +1 more source

Turning on Selective H2S Gas Sensing Activity in Ternary Nickel Tungstate Strongly Correlated Electron System Through Sub‐Gap Band Manipulation

Advanced Functional Materials, EarlyView.
A strongly correlated electron system (SCES) exhibits pronounced insulating behavior due to Coulombic repulsion between cations, which generates a charge gap. This study investigates the tuning of the band structure in NiWO4‐based SCES via Cu doping at substitutional sites and Li doping at interstitial sites.
Seung Yong Lee, Ha Eun Choa, Seung Joon Choi, Chul Oh Park, Gi Hyun Park, June Won Suh, Si Hoon Jeong, Yunseong Ji, Changhyun Jin, Jeong Yun Hwang, Inseo Kim, Jihye Park, Joonho Bang, Myung Sik Choi, Hyo‐Jick Choi, Dong Won Chun, Kimoon Lee, Wooyoung Lee, Kyu Hyoung Lee   +18 more
wiley   +1 more source

Sono‐Piezo‐Photosynthesis of Ethylene and Acetylene from Bioethanol under Ambient Conditions

Advanced Functional Materials, EarlyView.
A novel sono‐piezo‐photocatalytic strategy enables the conversion of bioethanol to ethylene (C2H4) and acetylene (C2H2) under ambient conditions, addressing the limitations of conventional methods that are high‐temperature and energy‐intensive. By using an advanced graphene oxide/sodium bismuth titanate heterostructure catalyst, this work achieved ...
Yue Jiang, Jiajun Zhang, Hongyang Ma, Shujie Zhou, Hsun‐Yen Lin, Sajjad S. Mofarah, Mark Lockrey, Teng Lu, Hangjuan Ren, Xiaoran Zheng, Maichael Gunawan, Suchen Huang, Yu‐Chun Huang, Fenglin Zhuo, Dali Ji, Judy N. Hart, Yun Liu, Jyh Ming Wu, Muthupandian Ashokkumar, Danyang Wang, Pramod Koshy, Charles C. Sorrell   +21 more
wiley   +1 more source

High‐Entropy Magnetism of Murunskite

Advanced Functional Materials, EarlyView.
The study of murunskite (K2FeCu3S4) reveals that its magnetic and orbital order emerges in a simple I4/mmm crystal structure with complete disorder in the transition metal positions. Mixed‐valence Fe ions randomly occupy 1/4 of the tetrahedral sites, with the remaining 3/4 being filled by non‐magnetic Cu+ ions.
Davor Tolj, Priyanka Reddy, Ivica Živković, Luka Akšamović, Jian Rui Soh, Kamila Komȩdera, Izabela Biało, Naveen Kumar Chogondahalli Muniraju, Trpimir Ivšić, Mario Novak, Oksana Zaharko, Clemens Ritter, Thomas LaGrange, Wojciech Tabiś, Ivo Batistić, László Forró, Henrik M. Rønnow, Denis K. Sunko, Neven Barišić   +18 more
wiley   +1 more source

Dynamic Networks via Polymerizable Deep Eutectic Monomers for Uniform Li+ Transport at Interfaces in Lithium Metal Batteries

Advanced Functional Materials, EarlyView.
The PDEM‐based SIGPE provides a dynamic nanophase from Li+‐bridged molecular self‐association, enhancing electrochemical stability and facilitating uniform Li+ ion flux at the interface. This unique solvation structure results in a hetero species‐driven inorganic‐rich SEI and long‐term cycle stability, suggesting that a PFAS‐free Li+‐containing monomer
Susung Yun, Seonho Kim, Puji Lestari Handayani, Sungyeb Jung, Jae Hyun Park, U Hyeok Choi   +5 more
wiley   +1 more source

Quantum Emitters in Hexagonal Boron Nitride: Principles, Engineering and Applications

Advanced Functional Materials, EarlyView.
Quantum emitters in hexagonal boron nitride have emerged as a promising candidate for quantum information science. This review examines the fundamentals of these quantum emitters, including their level structures, defect engineering, and their possible chemical structures.
Thi Ngoc Anh Mai, Md Shakhawath Hossain, Nhat Minh Nguyen, Yongliang Chen, Chaohao Chen, Xiaoxue Xu, Quang Thang Trinh, Toan Dinh, Toan Trong Tran   +8 more
wiley   +1 more source

Complex Oxide‐metal Hybrid Metamaterials with Integrated Magnetic and Plasmonic Non‐noble Metal Nanostructures

Advanced Functional Materials, EarlyView.
A new alloy‐oxide vertically aligned nanocomposite (VAN) thin film with two immiscible non‐noble metal elements of Co and Cu embedded in BaTiO3 (BTO) matrix is designed and fabricated, which presents interesting magnetic, ferroelectric, and optical properties.
Jijie Huang, Bin Zhang, Danny Hermawan, Alfredo Sanjuan, Benson Kunhung Tsai, Jialong Huang, R. Edwin Garcı́a, Haiyan Wang   +7 more
wiley   +1 more source