Results 271 to 280 of about 3,732,130 (405)

Structural Exploration of Zirconium Metal–Organic Frameworks Through Linker Desymmetrization and Modulator Compensation

open access: yesAdvanced Materials, EarlyView.
A linker‐desymmetrization‐modulator‐compensation (LDMC) strategy for constructing structurally diverse Zr‐MOFs is reported. This approach reduces linker symmetry to create defects in Zr‐clusters, which can be compensated for by modulator coordination. Using this approach, we synthesized PCN‐1005 and PCN‐1006, featuring unprecedented Zr‐clusters. In PCN‐
Rong‐Ran Liang   +8 more
wiley   +1 more source

Electrochemical Carbon Dioxide Reduction to Methanol on Copper‐Based Catalysts: Mechanistic Insights and Industrial Prospects

open access: yesAdvanced Materials, EarlyView.
This review presents a focused and integrated perspective on copper‐based catalysts for the selective electrochemical reduction of CO2 to methanol. It elucidates active site dynamics, mechanistic pathways, and structure–activity relationships, while connecting fundamental insights with catalyst design, reactor engineering, and techno‐economic ...
Debabrata Bagchi   +7 more
wiley   +1 more source

Active Learning‐Guided Accelerated Discovery of Ultra‐Efficient High‐Entropy Thermoelectrics

open access: yesAdvanced Materials, EarlyView.
An active learning framework is introduced for the accelerated discovery of high‐entropy chalcogenides with superior thermoelectric performance. Only 80 targeted syntheses, selected from 16206 possible combinations, led to three high‐performance compositions, demonstrating the remarkable efficiency of data‐driven guidance in experimental materials ...
Hanhwi Jang   +8 more
wiley   +1 more source

Stabilizing Frustrated Phase Transitions in Selective Oxidation Reactions

open access: yesAdvanced Materials, EarlyView.
Using multimodal operando spectromicroscopy, the frustrated phase transition responsible for selective oxidation over cobalt oxide spinel catalysts is identified, corresponding to combined surface reaction and Mars‐van Krevelen (MvK) dynamics. This regime is disrupted by the formation of mobile vacancies and the depletion of active oxygen at high ...
Luis Sandoval‐Diaz   +11 more
wiley   +1 more source

PORFC: Return and Returnless Type of Portable Fuel Weight Consumption Meter

open access: diamond, 2019
Rifqi Irzuan Abdul Jalal   +6 more
openalex   +1 more source

High‐Performance Zero‐Gap Glycerol‐Fed Electrolyzer for C3 Chemicals and Hydrogen Production

open access: yesAdvanced Materials, EarlyView.
This work presents a dynamic, self‐regulating operation strategy that enables selective glycerol electrooxidation in the OER‐free regime, co‐producing C3 chemicals and hydrogen at cell voltages below 1.25 V. Voltage‐ and temperature‐resolved analyses define optimal operating conditions, achieving a sustained current density of 500 mA cm−2 at ∼1.21 V ...
Shayan Angizi   +11 more
wiley   +1 more source

Advanced Porous Materials for Maritime Carbon Capture

open access: yesAdvanced Materials, EarlyView.
Carbon capture from emission sources, such as marine vessels, has attracted significant attention over the years. To achieve this goal, sorbents such as metal–organic frameworks (MOFs), porous polymer networks (PPNs), covalent organic frameworks (COFs), and their post‐synthetic modifications are currently being explored.
Kelechi Festus   +6 more
wiley   +1 more source

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