Results 151 to 160 of about 87,609 (269)
We demonstrated a mild and efficient approach for the generation of unstabilized radicals such as vinyl, methyl, heteroaryl, and cyclopropyl radicals from the corresponding easy‐to‐handle boronic esters to enable C─C bond formation with alkenes in a two‐molecule photoredox system without transition metals.
Ryoga Hashimoto +6 more
wiley +1 more source
FLP Mediated Conversion of Difluorobenzylalkynes to Fluoroallenyl Oniums via an SN1’ Pathway
Frustrated Lewis pair (FLP) selective C‒F activation of difluorobenzylalkynes allows the formation of fluoroallenic oniums via an SN1’ substitution pathway. The fluoroallenic onium salts are synthetic precursors that allow subsequent functionalization at allenic and onium positions.
Max Coles +6 more
wiley +1 more source
Replacing precious‐metal hydrogenation catalysts with sustainable iron systems is becoming a central challenge in catalysis. This predictive computational study reveals how rational redesign of Knölker‐type iron complexes dramatically enhances catalytic performance.
Carles Alcaide +6 more
wiley +1 more source
This work presents novel enamine‐based self‐assembling monolayers with engineered anchoring groups as hole‐selective contacts for inverted perovskite solar cells. The conjugated molecular design suppresses interfacial defects, optimizes charge extraction, and prevents aggregation.
Deimante Krisiune +11 more
wiley +1 more source
Single‐cell, spatial, molecular, and pathology analyses identify a CDH3‐associated malignant epithelial state in thymic epithelial tumors. This state links stem‐like and EMT programs to M2 macrophage–rich immunosuppressive niches, genomic instability, poor survival, and drug vulnerability.
Yuntao Feng +13 more
wiley +1 more source
Objective Immune complexes (ICs), formed by autoantigen and autoantibody, play a pathogenic role in systemic autoimmune diseases through stimulation of Fcγ receptors (FcγR). However, studies investigating bioactivity of circulating ICs across various diseases remain limited.
Koji Suzuki +8 more
wiley +1 more source
Ultrasonographic Demonstration of Severe Right-Sided Colitis in Concurrent Enterohemorrhagic <i>Escherichia coli</i> O157 and <i>Campylobacter jejuni</i> Infection. [PDF]
Kubota K, Hayashi K, Midori Y.
europepmc +1 more source
Abstract Background Due to exposure to high levels of scattered ionizing radiation, interventional radiology (IR) physicians have an elevated risk of radiation‐induced eye injuries and cataracts. Previous studies have evaluated the protective effects of regular lead glasses and recommended measures to improve radiation protection for the eyes. However,
Ryota Shindo +5 more
wiley +1 more source
Correction: Relationship Between Qualitative Differences in Discourse Impairment and Theory of Mind in Patients With Right Hemisphere Damage: A Case Series. [PDF]
Hoyano K, Kobayashi Y.
europepmc +1 more source
Molecular dynamics and density functional theory simulations reveal that azorubine (E122) is strongly chemisorbed onto γ‐Al2O3 (radial distribution function distances <3.5 Å), with form 2 showing the highest adsorption energy (−917.107 kcal/mol). Noncovalent interactions (NCI)/reduced density gradient and HOMO–LUMO analyses identify the active sites ...
Anouar Ameziane El Hassani +6 more
wiley +1 more source

