Results 101 to 110 of about 50,608 (301)

Diamondiyne: A 3D Carbon Allotrope With Mixed sp–sp3 Hybridization

Angewandte Chemie, EarlyView.
A new carbon allotrope with mixed sp–sp3 hybridization has been synthesized through delicately controlled kinetics at a liquid–liquid interface. The resulting material, termed diamondiyne, exhibits an expanded diamond‐type network in the form of small crystallites in a continuous all‐carbon film.
Yizhou Yang, Jie Xu, Yanyan Chen, Yu Xia, Sami Zeliouche, Clara Schäfer, Martin Ratsch, Ebba Matic, Martin Rahm, Lars Evenäs, Angela Beth Grommet, Tom Willhammar, Karl Börjesson   +12 more
wiley   +2 more sources

Self-assembled palladium nanoflowers supported on fullerene: Electrochemical catalytic performance for the reduction of 4-nitrophenol

Electrochemistry Communications, 2019
Loading metal nanoparticles on the surface of nanosheet supports is an attractive approach to enhancing their catalytic performance. Herein, palladium nanoflowers (Pd NFs) were prepared on amino-functionalized fullerene (C60-NH2) by hydrothermal self ...
Zhongping Li, Yuxin Zhang, Ruiqi Zhu, Guangming Wen, Chuan Dong, Hung-Wing Li   +5 more
doaj   +1 more source

Pairing Non‐Fullerene Acceptors With the Right Polymer: Impact of Phase Morphology and Short‐Range Transport on Charge Generation

Advanced Electronic Materials, EarlyView.
This study investigates polymer requirements for pairing with high‐efficiency non‐fullerene acceptors (NFA) in organic photovoltaics by comparing three polymer blends across varied phase morphologies. The generation of free charges is driven by fast transport‐assisted charge separation combined with slow intrinsic recombination.
Yufei Zhong, Gareth John Moore, Subhrangsu Mukherjee, Yanfang Geng, Nikolaos Droseros, Martina Causa’, Lee J. Richter, Dean M. DeLongchamp, Erjun Zhou, Natalie Banerji   +9 more
wiley   +1 more source

Structure and Function of a Multi‐Megadalton Virus‐Like Proteolytic Dodecahedron

Angewandte Chemie, EarlyView.
Zuzalysin, a virulence metallopeptidase of the periodontal pathogen Porphyromonas gingivalis, is secreted as a latent, flexible ≈95‐kDa monomer. Calcium triggers cysteine‐switch activation and hierarchical assembly into pentamers, bipentamers, tripentamers, and a ≈5.6‐MDa, ≈355‐Å dodecahedron. Structures at 1.8–3.6 Å reveal a virus‐sized catalytic cage
Mariusz Madej, Arturo Rodríguez‐Banqueri, Danuta Mizgalska, Borys Szmigielski, Zuzanna Nowakowska, Małgorzata Benedyk‐Machaczka, Monika Bzowska, Katarzyna Mikruta, Juan Sebastián Ramírez‐Larrota, Chinanu Agunanne, Olivier Julien, Anthony J. O'Donoghue, Carsten Scavenius, Mario López‐Martín, Enrique Marcos, Łukasz Koziej, Sebastian Glatt, Pablo Guerra, Ulrich Eckhard, Jan Potempa, F. Xavier Gomis‐Rüth   +20 more
wiley   +2 more sources

Design, synthesis, and electrochemical studies of a new [60] fullerene pyrrolidine as a precursor for the construction of supramolecular systems

Revista de la Academia Colombiana de Ciencias Exactas, Físicas y Naturales, 2023
One of the challenges in fullerene chemistry is to prepare derivatives soluble in common solvents to study their chemical and physical properties in solution. In this context, a new highly soluble fullerene adduct was synthesized by the cycloaddition of
Gabriel Martinez, Christian C. Carmona Vargas, Manuel N. Chaur   +2 more
doaj  

C60 fullerene and its nanocomplexes with anticancer drugs modulate circulating phagocyte functions and dramatically increase ROS generation in transformed monocytes

Cancer Nanotechnology, 2018
Background C60 fullerene-based nanoformulations are proposed to have a direct toxic effect on tumor cells. Previous investigations demonstrated that C60 fullerene used alone or being conjugated with chemotherapeutic agents possesses a potent anticancer ...
Larysa M. Skivka, Svitlana V. Prylutska, Mariia P. Rudyk, Nataliia M. Khranovska, Ievgeniia V. Opeida, Vasyl V. Hurmach, Yuriy I. Prylutskyy, Leonid F. Sukhodub, Uwe Ritter   +8 more
doaj   +1 more source

Self-Assembled Monolayers on Gold Surfaces of Ferrocene-BODIPY-Fullerene-Helical Peptide Conjugates: Studies of Electron Transfer Processes by Ultra-Fast Electrochemistry. [PDF]

J Pept Sci
Three ferrocene‐BODIPY‐C60‐peptides (T1–T3) were synthesized and grafted on gold surfaces to form self‐assembled monolayers. Calculation of the tilt angles and surface density of these SAMs using PM‐IRRAS and ultrafast electrochemical experiments revealed that less vertically oriented and densely packed monolayers were obtained compared with previously
Rabah J, Vallée A, Fensterbank H, Ha-Thi MH, Méallet R, Boujday S, Maisonhaute E, Wright K, Allard E.   +8 more
europepmc   +2 more sources

From Laboratory to Industry: Evaporating Functional Layers at High Rates for Fully Textured Perovskite/Silicon Tandems

Advanced Energy Materials, EarlyView.
Perovskite/silicon tandem solar cells exhibit outstanding efficiencies; however, the development of scalable and high‐throughput manufacturing processes remains a critical challenge. Here, we demonstrate accelerated deposition of multiple functional layers via high‐rate thermal evaporation without compromising film quality or device performance.
Bhushan P. Kore, Oliver Fischer, Mohamed A. A. Mahmoud, Martin Bivour, Stefan W. Glunz, Juliane Borchert   +5 more
wiley   +1 more source

Conformationally Switchable Copper(I) Complexes Amplify BODIPY Triplet Photosensitization

Angewandte Chemie, EarlyView.
Coupling a structurally switchable Cu(I) complex to an organic light‐harvesting chromophore boosts photoinduced intersystem crossing via the transient formation of a Cu(II) intermediate. Spectroscopic, physical, computational, and photocatalytic studies support this unique new approach to solar energy upconversion.
Nisha Kamboj, Annabella DeBernardo, Margaret G. Lekan, Nicholas E. Jackson, Lisa Olshansky   +4 more
wiley   +2 more sources

ON (3,6) AND (4,6) - FULLERENE CAYLEY GRAPHS [PDF]

, 2016
An (r, s)-fullerene graph is a planar 3-regular graph with only Cr and Cs faces, where Cn denotes a cycle of length n. In this paper, the (3,6)-fullerene Cayley graphs constructed from finite groups are classified.
LOGHMAN, Amir, ASHRAFI, Ali Reza, MOGHARRAB, Mojgan   +2 more
core   +2 more sources