Results 121 to 130 of about 28,098 (250)

Tribenzotriquinacene Fused Dimers ("Fusodimers")-Synthesis and Host-Guest Properties. [PDF]

open access: yesChemistry
Two tribenzotriquinacene units merged with each other in either syn‐ or anti‐orientation of the bowls have become accessible in a short synthesis. In contrast to the anti‐isomer, the syn‐isomer forms 1:1 host–guest complexes with both C60 and C70 in solution and in the solid state, as shown by 1H NMR spectroscopy and x‐ray diffraction.
Ng CF   +5 more
europepmc   +2 more sources

Higher Fullerenes: Structure and Properties

open access: yes, 1994
The structures of higher fullerenes are described based on 13C NMR measurements of isolated and purified samples. The most interesting aspect deduced from the present structural work on the higher fullerenes up to C90 is that among 19 kinds of fullerenes
Koichi Kikuchi   +5 more
core   +1 more source

A Convergent Materials Design Paradigm Across Electro‐ and Photocatalysis for Sustainable Hydrogen Peroxide Production

open access: yesCarbon Energy, EarlyView.
This review outlines advanced modification strategies for electrocatalytic and photocatalytic H2O2 production, covering bandgap tuning, defect engineering, heterostructure construction, cocatalyst loading, and functional framework design. Structure‐performance correlations are revealed across catalysts such as metal oxides, sulfides, carbon nitrides ...
Na Li   +9 more
wiley   +1 more source

Purification of small bandgap fullerenes

open access: yes, 1997
A process for purification of the previously insoluble empty fullerenes and endohedral metallofullerenes was developed, based on sublimation from the soot and subsequent solubilization by electrochemical reduction.
Diener, Michael Daniel
core  

Regioisomerism Rewires Optical and Ion Recognition Properties in Azulenylsumanenes—Curved Non‐Alternant π‐Systems

open access: yesChemistry – A European Journal, EarlyView.
Regioisomerism rewires orbital topology and electronic polarity in curved non‐alternant π‐systems, switching both optical response and alkali metal ion recognition from Na+ to Rb+ selectivity. ABSTRACT Herein, we explore the fundamental concept of combining the molecular curvature of a molecular fragment of buckminsterfullerene with the pronounced ...
Jakub Cyniak   +4 more
wiley   +1 more source

Benzylic Oxidation of Pillar[5]Arene: From Homo‐ to Cross‐Conjugated Macrocyclic Systems

open access: yesChemistry – A European Journal, EarlyView.
Selective benzylic oxidations of pillar[5]arene have been carried out to generate all the possible oxidized derivatives containing from one up to five carbonyl subunits. Effects resulting from the homo‐ and the cross‐conjugation within this series of compounds have been investigated in details and analyzed with the help of DFT calculations.
Jorge Juan Marco‐Guimbao   +8 more
wiley   +1 more source

Synthesis, Structures, and Properties of Cyclopenta‐Fused Anthra[1,2‐a]anthracene Derivatives as New Polycyclic Aromatic Compounds

open access: yesChemistry – A European Journal, EarlyView.
Three new polycyclic aromatic compounds consisting of one or two five‐membered rings were synthesized by Scholl reaction or Pd‐catalyzed cyclization from fused anthracene derivatives. X‐ray analysis and DFT calculations revealed that these compounds have slightly twisted or curved structures.
Moe Kobayashi   +7 more
wiley   +1 more source

Chiral Cycloparaarylenes Incorporating Binaphthyl Units: Dramatic Effects of Peripheral Functionalization on (Chir)Optical Properties

open access: yesChemistry – A European Journal, EarlyView.
Chiral cycloparaarylenes (CPAs) incorporating binaphthyl units were synthesized. The methoxy‐substituted and methylenedioxy‐bridged systems adopt D3‐ and C3/C1‐symmetric structures, respectively. They exhibited distinct solid‐state emission and aggregation‐induced emission enhancement (AIEE).
Kazuto Takaishi   +3 more
wiley   +1 more source

Fe–Ca‐Catalyzed Conversion of Cellulose Into Highly Ordered Graphitic Carbon Revealed by Solid‐State 13C NMR and Mössbauer Spectroscopy

open access: yesChemistry – A European Journal, EarlyView.
New insights into the mechanism of the structural transformation of cellulose into highly ordered graphitic carbon using an Fe–Ca bimetallic catalyst were obtained through complementary spectroscopic techniques, including Raman, solid‐state NMR, and Mössbauer.
Shamala Gowri Krishnan   +3 more
wiley   +1 more source

Scientometric portrait of Nobel Laureate Harold W. Kroto [PDF]

open access: yes, 2002
Scientometric analysis of 190 publications by Harold W. Kroto, the Nobel laureate in Chemistry (1996) published during 1985 -2000 in domains: Fullerenes (109), Cluster Science (39) , Spectroscopy of Unstable Species and Reaction Intermediates (8 ...
Kademani, B. S.   +2 more
core  

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