Results 181 to 190 of about 53,712 (256)

Cycloazulenylene

open access: yesAngewandte Chemie International Edition, EarlyView.
A strained macrocycle consisting solely of azulene subunits, named [6]cycloparaazulenylene ([6]CPA), is presented. The macrocycle exhibits a notably narrow HOMO–LUMO gap for a pristine azulene species, strain‐induced red‐shifted absorption, and an unusual tubular packing motif elucidated via single‐crystal XRD.
Clara Douglas   +8 more
wiley   +1 more source

Photogenerated Oxetanes as a Gateway to Uphill Cyclopropanation

open access: yesAngewandte Chemie International Edition, EarlyView.
An atom‐economical route to densely functionalized cyclopropanes from furans and photochemically activated aldehydes is enabled by a unique oxetane‐to‐cyclopropane rearrangement. These cyclopropanes can be used to access complex bioactive scaffolds and serve as a platform for asymmetric cyclopropane synthesis.
Tim Köglmeier   +2 more
wiley   +1 more source

Environmental and Genetic Effects on the Composition of Palm Oil From Hybrid Plant Clones of Caiaué and Oil Palm

open access: yesJournal of the American Oil Chemists' Society, EarlyView.
ABSTRACT The interspecific hybrids (IEH OxG) obtained from the crossing of Elaeis oleifera (Eo) and Elaeis guineensis (Eg) are resistant to some diseases that affect Eg in some regions of South America, and commercial growing in several countries has been established.
Rosemar Antoniassi   +6 more
wiley   +1 more source

Design Considerations for Polymer–Deep Eutectic Solvent Hybrid Systems for Transdermal Drug Delivery

open access: yesJournal of Applied Polymer Science, EarlyView.
Deep eutectic solvents (DESs) act as tunable, green excipients that modulate polymer structure–property relationships to enhance drug solubility, skin permeation, stability, and controlled release. Through hydrogen‐bond interactions, DES–polymer hybrid systems enable improved transdermal performance, offering a rational, design‐driven platform for ...
Madhavi Kailas Kapale   +3 more
wiley   +1 more source

Valorization of Post‐Consumer Waste From Metallized Flexible Packaging and Industrial EPM Waste: Development of Sustainable Composites

open access: yesJournal of Applied Polymer Science, EarlyView.
Post‐consumer metallized flexible packaging waste and industrial EPM waste are transformed into sustainable composites through mechanical recycling. The incorporation of 30 wt% EPM provides the most favorable balance between stiffness, ductility, and impact resistance, achieving 53.36 kJ/m2.
Tiago O. Oliveira   +2 more
wiley   +1 more source

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