Results 121 to 130 of about 40,153 (337)
A femtosecond UV pump–probe microscope resolves binding‐induced changes in protein excited‐state dynamics and converts these intrinsic contrasts into an equilibrium affinity readout. By probing tryptophan responses directly in solution, the approach enables quantitative determination of dissociation constants without labeling or immobilization ...
Jianghao Shen +5 more
wiley +1 more source
Photochemical N‐dealkylation of Tertiary Amines Coupled With Photocharging of Poly(Heptazine Imides)
Protonated poly(heptazine imide) (H‐PHI) functions as an energy reservoir, thereby facilitating the endothermic dealkylation of triethylamine through a proton‐coupled two‐electron transfer (PC2ET) process. The extent of photocharging is quantitatively described by a molecular‐level descriptor, Ne:Nhept, providing a direct correlation between stored ...
Jingru Zhuang +6 more
wiley +2 more sources
Scaling laws for ring-shaped beam profiles in laser-based powder bed fusion of metals
The application of alternative beam shapes is a current research trend to stabilize and accelerate the laser-based powder bed fusion of metals process. Although many publications show a reduced process dynamic and an enlargement of the process window for
Jonas Grünewald +2 more
doaj +1 more source
Phase Diagrams and Piezoelectric Properties of Wurtzite Al1−x−yScxGdyN Heterostructural Alloys
This study demonstrates ferroelectricity and piezoelectric properties improvement of quaternary wurtzite Al1−x−yScxGdyN${\rm Al}_{1-x-y}{\rm Sc}_x{\rm Gd}_y{\rm N}$ films, guided by density functional theory calculations. Wurtzite Al1−x−yScxGdyN${\rm Al}_{1-x-y}{\rm Sc}_x{\rm Gd}_y{\rm N}$ films have a high optical bandgap, enhanced piezoelectric ...
Julia L. Martin +11 more
wiley +1 more source
Geometry Controls Confined Water Dynamics in Lipidic Mesophases
An archaeal‐inspired lipidic mesophase allows precise control of interfacial curvature and water‐channel connectivity. Combining structural, thermodynamic, and ultrafast spectroscopies, we reveal that curvature governs the structure and reorientation dynamics of confined water, establishing a molecular‐level link between topology and dynamics in soft ...
Sara Catalini +7 more
wiley +2 more sources
Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds and Ionic Liquids. Sublimation, Vaporization, and Fusion Enthalpies from 1880 to 2015. Part 2. C11–C192 [PDF]
William E. Acree, James S. Chickos
openalex +1 more source
By grafting dense long double‐brush chains, we synthesized bottlebrush networks with high theoretical enthalpy. Their low entanglement, combined with dynamic bonds, promotes crystalline domain reorganization and minimizes enthalpy loss, achieving a record enthalpy of 240.7 J·g−1.
Qiguang Liu +7 more
wiley +1 more source
Non‐Equilibrium Synthesis Methods to Create Metastable and High‐Entropy Nanomaterials
ABSTRACT Stabilizing multiple elements within a single phase enables the creation of advanced materials with exceptional properties arising from their complex composition. However, under equilibrium conditions, the Hume–Rothery rules impose strict limitations on solid‐state miscibility, restricting combinations of elements with mismatched crystal ...
Shuo Liu +3 more
wiley +1 more source
Melt-quenched carboxylate metal–organic framework glasses
Although carboxylate-based frameworks are commonly used architectures in metal-organic frameworks (MOFs), liquid/glass MOFs have thus far mainly been obtained from azole- or weakly coordinating ligand-based frameworks. This is because strong coordination
Minhyuk Kim +5 more
doaj +1 more source
This review provides a bottom‐up evaluation of sodium‐ion battery safety, linking material degradation mechanisms, cell engineering parameters, and module/pack assembly. It emphasizes that understanding intrinsic material stability and establishing coordinated engineering control across hierarchical levels are vital for preventing degradation coupling ...
Won‐Gwang Lim +5 more
wiley +1 more source

