Photochemical Cyclization of Tertiary Buta‐2,3‐dienamides to β‐Lactams Upon Triplet Energy Transfer
Energy transfer is the key to the successful photocyclization of the title compounds to 3,4‐disubstituted 2‐azetidinones. If the substituent at the nitrogen atom is primary (R2 = H), trans products are formed exclusively. The triplet state of xanthen‐9‐one (XT) was found to be quenched by an allene amide (R, R2 = H, R1 = Bn, and R3 = Ph) with a ...
Johannes Hofer +3 more
wiley +2 more sources
Assessing the risk spillover effects between the Chinese carbon market and the US-China energy market. [PDF]
Yan J, Işık C.
europepmc +1 more source
Urban birds' detectability is affected by inter‐ and intraspecific variation in shyness
Detection probabilities differ between bird species as a function of their life history and ecological and behavioural traits, inevitably introducing bias in their abundance and occupancy estimates. However, the effects of behavioural traits such as species shyness and vigilance on detectability remain poorly understood.
Peter Mikula +3 more
wiley +1 more source
Using smart transportation assets to hedge fossil energy markets: Evidence from quantile-based VAR approach. [PDF]
Hasan MB +5 more
europepmc +1 more source
Financial Time Series Uncertainty: A Review of Probabilistic AI Applications
ABSTRACT Probabilistic machine learning models offer a distinct advantage over traditional deterministic approaches by quantifying both epistemic uncertainty (stemming from limited data or model knowledge) and aleatoric uncertainty (due to inherent randomness in the data), along with full distributional forecasts.
Sivert Eggen +4 more
wiley +1 more source
Multiscale neural dynamics in sleep transition volatility across age scales: a multimodal EEG-EMG-EOG analysis of temazepam effects. [PDF]
Sirpal P, Sikora WA, Refai HH.
europepmc +1 more source
The Monetary Policy–Commodities Nexus: A Survey
ABSTRACT This survey synthesizes evidence on the bidirectional links between commodity markets and monetary policy. On the commodities‐to‐policy side, we review how shocks to energy, food, and metals pass through to inflation, inflation expectations, economic activity, and financial stability in state‐dependent ways that vary by shock type, exposure ...
Martin T. Bohl +2 more
wiley +1 more source
Examining the safe-haven and hedge capabilities of gold and cryptocurrencies: A GARCH and regression quantiles approach in geopolitical and market extremes. [PDF]
Ben Ameur H, Jamaani F, N Abu Alfoul M.
europepmc +1 more source
Climate variability, population growth, and globalization impacting food security in Pakistan. [PDF]
Abbas S +11 more
europepmc +1 more source
Recurrent Neural Network GO-GARCH Model for Portfolio Selection. [PDF]
Burda M, Schroeder AK.
europepmc +1 more source

