Titanium Suboxides Responsible for Electronic Anomaly Near Room Temperature in the Ti3C2Tx MXene
Our multi‐technique study reveals that the near‐room‐temperature anomaly in Ti3C2Tx MXene is linked to titanium suboxide nanodomains, including Ti3O5, embedded within the MXene host. Their temperature‐driven transformation provides an alternative explanation to solvent‐ and swelling‐based models and offers new insight into the thermally activated ...
Bence G. Márkus +8 more
wiley +1 more source
Effects of Diet Composition and Yeast Cell Wall Supplementation on Ruminal Fermentation, Gas Kinetics, Methane Production and Digestibility Assessed In Vitro Using Gas Production and Daisy<sup>II</sup> Incubator Systems. [PDF]
Ramay MS, Bundur A, Riaz R, Sızmaz Ö.
europepmc +1 more source
Solution‐processed Cu(bdc) forms prototypical MOF thin films for which a multitude of not fully satisfactory structural models have been suggested. Combining rotating grazing‐incidence diffraction and X‐ray reflectivity on two complementary samples with density‐functional theory, we first discard the previously suggested models and then identify a non ...
Narges Taghizade +7 more
wiley +1 more source
Source Attribution of Elevated Ethane Concentrations Detected by Regional Monitors in Oil and Gas Production Regions. [PDF]
Graves JD +6 more
europepmc +1 more source
Terminal groups on Cu porphyrins modulate the electronic states of single‐atom Cu centers through a long‐range electronic effect, without altering the Cu coordination geometry. Meanwhile, a multi‐descriptor framework is established that incorporates porphyrin regulation, hybrid catalyst properties, and CO2 photoreduction capabilities.
Yi Zhang +13 more
wiley +1 more source
Sulfur fluoride exchange (SuFEx) is a powerful click platform, yet water‐compatible multifunctional linchpins remain elusive. Here, we report decagram‐scalable diazonium linchpins that enable rapid Pd‐catalyzed diversification and direct, catalyst‐free on‐DNA ligation in aqueous media.
Seok Ju Hong +5 more
wiley +1 more source
Extreme Sensitivity of Greenhouse Gas Production in Mineral Wetland Sediments under Multiple Salinization Regimes. [PDF]
Valizadeh S +3 more
europepmc +1 more source
This article details the development of an artery‐on‐chip platform for in vitro arterial disease modeling and therapeutic discovery. It describes the fabrication of a fibrin biomaterial scaffold seeded with iPSC‐derived smooth muscle and endothelial cells, mimicking native artery properties. Two genetic disease models showcase the platform's ability to
Danielle Yarbrough +10 more
wiley +1 more source
Date palm seed-derived biochar as an environmentally sustainable feed supplement in cattle: impacts on gas production, methane emissions, fermentation parameters and performance predictions. [PDF]
Ghazzawy HS +9 more
europepmc +1 more source
Toward Fast Proton Shuttling in Acidic Oxygen Evolution Reaction
This review establishes proton transfer dynamics as a descriptor governing acidic OER activity, moving beyond the kinetic constraints derived from the proton coupled electron transfer. We discuss how deprotonation governs classical mechanisms, including adsorbate evolution mechanism (AEM), lattice oxygen mechanism (LOM) and oxide path mechanism (OPM ...
Ashish Gaur +3 more
wiley +1 more source

