Results 111 to 120 of about 175 (149)

Probing Metal Tip‐Induced Bond Weakening of a Reactive Alkyne Center Aligned via a Rigid Triphenylmethane‐Based Tripod on Au(111) by TERS and DFT

open access: yesJournal of Raman Spectroscopy, EarlyView.
We investigate tip‐induced bond weakening of a single alkyne center immobilized and aligned upright on Au(111) using a rigid triphenylmethane‐based tripod. By varying the tip–molecule distance, we observe shifts in the ≡C–H and –C≡C– vibrational bands via ultrahigh vacuum low‐temperature tip‐enhanced Raman scattering (TERS).
Gang Li   +12 more
wiley   +1 more source

Frozen Differential Scattering in Reconfigurable Complex Media

open access: yesLaser &Photonics Reviews, EarlyView.
A localized perturbation universally results in a rank‐one update of the scattering matrix of any complex medium. The resulting differential output wavefront is “frozen”: its spatial pattern is fixed (agnostic to the input wavefront). Experiments with a programmable‐metasurface‐parametrized wireless link validate frozen differential scattering and ...
Philipp del Hougne
wiley   +1 more source

Doping‐Free Polymer Nanoparticle Engineering of n‐Type Organic Mixed Ion–Electron Conductors for Enhancement‐Mode Organic Electrochemical Transistors

open access: yesMacromolecular Rapid Communications, EarlyView.
We report a nanoparticle formulation strategy for the ladder polymer BBL that enables undoped enhancement‐mode OECTs. Controlled reprecipitation with DBSA yields stable nanoparticles, and spray‐coating forms dense, well‐connected films. The resulting devices exhibit strongly enhanced electrochemical response and transconductance, establishing a ...
Shunsuke Yamamoto   +2 more
wiley   +1 more source

On Bounds for Norms of Reparameterized ReLU Artificial Neural Network Parameters: Sums of Fractional Powers of the Lipschitz Norm Control the Network Parameter Vector

open access: yesMathematical Methods in the Applied Sciences, EarlyView.
ABSTRACT It is an elementary fact in the scientific literature that the Lipschitz norm of the realization function of a feedforward fully connected rectified linear unit (ReLU) artificial neural network (ANN) can, up to a multiplicative constant, be bounded from above by sums of powers of the norm of the ANN parameter vector.
Arnulf Jentzen, Timo Kröger
wiley   +1 more source

DiffBP: generative diffusion of 3D molecules for target protein binding. [PDF]

open access: yesChem Sci
Lin H   +9 more
europepmc   +1 more source

Asymptotic Analysis of the Static Bidomain Model for Pulsed Field Cardiac Ablation

open access: yesMathematical Methods in the Applied Sciences, EarlyView.
ABSTRACT Cardiac arrhythmias are caused by faulty electrical signals in the heart, which lead to chaotic wave propagation and impaired cardiac function. This work focuses on a non‐thermal ablation technique based on electroporation (EP), a promising method for treating arrhythmias, called pulsed field ablation (PFA).
Annabelle Collin   +2 more
wiley   +1 more source

On the Mean‐Field Limit of Consensus‐Based Methods

open access: yesMathematical Methods in the Applied Sciences, EarlyView.
ABSTRACT Consensus‐based optimization (CBO) employs a swarm of particles evolving as a system of stochastic differential equations (SDEs). Recently, it has been adapted to yield a derivative free sampling method referred to as consensus‐based sampling (CBS). In this paper, we investigate the “mean‐field limit” of a class of consensus methods, including
Marvin Koß, Simon Weissmann, Jakob Zech
wiley   +1 more source

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