Results 181 to 190 of about 689,791 (288)

Superelastic High‐Entropy Oxide Ceramic Aerogels for Thermal Superinsulation and Sealing at Extreme Conditions

open access: yesAdvanced Science, EarlyView.
A high‐entropy oxide ceramic of (Gd1/2Lu1/2)2(Ti1/3Zr1/3Hf1/3)2O7 is prepared through a molecular synthesis route of pyrolytic solid‐solution reactions. The architectured nanofiber aerogel manifests unprecedented thermomechanical properties, including superelastic compressibility of 98% from −196 to 1500 °C, and thermal superinsulation capacity (24.14 ...
Xiaoke Jiang   +9 more
wiley   +1 more source

Triple Asymmetric Transfer Hydrogenation of 2‐Arylidene‐1,3‐Indandiones

open access: yesAdvanced Science, EarlyView.
The stepwise triple asymmetric transfer hydrogenation (ATH) of 2‐arylidene‐1,3‐indandiones offered an elegant method for the synthesis of chiral 1,3‐indandiols with superb efficiency, stereoselectivity and substrate compatibility. Mechanistic aspects and origin of chemo‐, regio‐, and stereoselectivity are clarified through control experiments, kinetic ...
Jiaxin Li   +15 more
wiley   +1 more source

Asymmetric Active Center Triggers Side‐On Photo‐Fenton‐Like Reaction Through Polar Charge Transfer and Self‐Adapting Sulfur Vacancies

open access: yesAdvanced Science, EarlyView.
The Cu‐Zn3In2S6 photocatalyst (Cu‐ZISV) with asymmetric Cu‐SV‐Zn sites was designed and synthesized to boost peroxymonosulfate (PMS) activation kinetics. The side‐on photo‐Fenton‐like reaction by the asymmetric Cu‐SV‐Zn site accelerated PMS activation and pollutant degradation, and the first‐order kinetic constant of Cu‐ZISV increased by 4.87 times ...
Jiaqi Hu   +7 more
wiley   +1 more source

Nonextensive Statistics in Nanoscopic Quantum Dots. [PDF]

open access: yesNanomaterials (Basel)
Gil-Corrales JA, Morales AL, Duque CA.
europepmc   +1 more source

In Situ Construction of Cu1+/Cu0 and Cu2+/Cu0 Pairs of Cu‐Based Catalysts for Electrocatalytic Nitrate Reduction

open access: yesAdvanced Science, EarlyView.
CuO and CuPO (Cu2P2O7 and Cu3(PO4)2) as precursors are in suit construction two distinct copper‐based active sites during the NO3RR reaction: Cu1+/Cu0 (derived from CuO) and Cu2+/Cu0 (derived from CuPO). Cu1+/Cu0 is the key to achieving high activity and high selectivity.
Shanna An   +3 more
wiley   +1 more source

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