Results 121 to 130 of about 5,638 (257)

Dual‐Substrate Synergistic Photocatalysis: Exogenous Reagent‐Free Co‐Removal of Phenol and Cr(VI) via Electron‐Donor‐Mediated Redox Coupling over Modified Carbon Nitride

open access: yesAdvanced Science, EarlyView.
An exogenous reagent‐free dual‐substrate strategy harnesses phenol as an intrinsic electron donor to drive synchronous phenol degradation and Cr(VI) reduction over modified carbon nitride. π–π stacking and hydrogen bonding direct electron transfer to the catalyst, enriching photogenerated electrons and accelerating Cr(VI) reduction 6.4‐fold. This waste‐
Xiaoman Zhang   +9 more
wiley   +1 more source

First-Principles Investigation of Phosphorus-Doped Graphitic Carbon Nitride as Anchoring Material for the Lithium-Sulfur Battery

open access: yesMolecules
The utilization of lithium–sulfur battery is hindered by various challenges, including the “shuttle effect”, limited sulfur utilization, and the sluggish conversion kinetics of lithium polysulfides (LiPSs).
Yuehui Chen   +10 more
doaj   +1 more source

Architecture‐Controlled Hierarchical Carbon‐Based Current Collector for Mitigating Interfacial Instabilities in Lithium‐Metal Anodes

open access: yesAdvanced Science, EarlyView.
A defect‐engineered, hierarchically porous carbon black/CNT current collector guides lithiophilic nucleation in 3D architecture. Steam‐created defects enable uniform Li plating, while CNTs provide conductivity and a lightweight framework, suppressing dendrites and side reactions for stable anode‐free cells.
Seo Hui Kang   +3 more
wiley   +1 more source

Imaging Electric Polarization Switching in Multilayer Graphene

open access: yesAdvanced Science, EarlyView.
Domain wall sliding‐induced electric polarization switching is directly observed for the first time in multilayer graphene, enabled by a novel optical readout method. The polarization switching is realized upon application of global and local electric fields, and mechanical forces between neighboring polar domains of opposite out‐of‐plane polarizations
Zhou Zhou   +10 more
wiley   +1 more source

Incorporation of Organic Counter‐Cations Into Poly(Heptazine Imide) Networks for Promoting Proton‐Coupled Electron Transfer During Photocatalytic H2O2 Evolution

open access: yesAngewandte Chemie, EarlyView.
Incorporation of N‐based onium ions into the ionic framework of poly(heptazine imide) was obtained via protonation‐deprotonation of PHI frameworks arising from a parent Na‐containing analogue. Particularly, methylammonium moieties, through their small molecular size, hydrogen bonding capabilities and rotational mobility, appear to stabilize ...
Dingqiao Ji   +6 more
wiley   +2 more sources

Beyond Percolation: Graphene‐Enabled Network Reinforcement Enhances Thermal Transport in Paraffin Phase‐Change Composites

open access: yesAdvanced Science, EarlyView.
Expanded‐graphite/graphene‐nanoplatelet hybrids deliver a near‐order‐of‐magnitude thermal‐conductivity enhancement in paraffin phase‐change materials. A microCT‐informed 3D modeling framework resolves the percolating EG backbone and captures sub‐voxel GNP enrichment, quantitatively linking microstructure to heat flow and revealing a graphene‐enabled ...
Thomas Hoke   +4 more
wiley   +1 more source

Graphdiyne as a Hole‐Transport Channel in Carbon Nitride Heterojunctions for Synergistic CO2 Reduction and γ‐Butyrolactone Synthesis

open access: yesAngewandte Chemie, EarlyView.
A fully metal‐free heterojunction constructed from graphdiyne (GDY) and polymeric carbon nitride (PCN) enables efficient coupling of CO2 reduction and tetrahydrofuran oxidation. GDY serves as a hole‐transport channel, establishing a built‐in electric field that drives spatial charge separation. The optimized catalyst achieves near‐unity selectivity for
Xuan Zhang   +7 more
wiley   +2 more sources

Beyond d‐Band Catalysis: A Critical Review and Descriptor Framework for Rare‐Earth Engineering in Lithium–Sulfur Batteries

open access: yesAdvanced Science, EarlyView.
Rare‐earth catalysts regulate lithium–sulfur battery chemistry through f‐orbital–mediated interactions, enabling simultaneous polysulfide adsorption and catalytic conversion on conductive carbon hosts. This synergistic control suppresses the shuttle effect, accelerates redox kinetics, and guides stable Li2S nucleation, providing a mechanistic framework
Fan Wang   +5 more
wiley   +1 more source

Controllable Carbon Shell Encapsulation via Rapid Joule Heating Calcination for High‐Performance Asymmetric Supercapacitor With Suppressed Self‐Discharge and Robust Cycling Stability

open access: yesAdvanced Science, EarlyView.
The H‐Fe3O4@C negative electrode and H‐NiCo2S4@C positive electrode are designed through a controllable carbon shell encapsulation strategy. The as‐constructed asymmetric supercapacitor presents robust cycling stability with 93.7% capacity retention after 25 000 cycles.
Qiang Zhou   +8 more
wiley   +1 more source

Engineering hollow fiber membranes with poly-m-aminophenol functionalized graphitic carbon nitride for efficient water purification

open access: yesCurrent Research in Green and Sustainable Chemistry
Water pollution caused by industrialization poses a great threat to the living organisms mainly due to the release of dye wastewater and pollutants into the water bodies. Ingestion of such polluted water has detrimental effects on living organisms.
Sooraj S. Nayak   +3 more
doaj   +1 more source

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