Results 1 to 10 of about 15,945 (209)

Manganese-catalysed C2 allylation and deuteration of indoles in water

Tetrahedron Green Chem, 2023
Mn-catalysed C–H activation has emerged as a useful sustainable methodology for the formation of new C–C bonds. To date most of the protocols are described in organic solvents.
Si Lok Ko, Eimear Courtney, Dr Mark Light, Dr David Jones, Dr Gerard P. McGlacken   +4 more
doaj   +1 more source

Ag–NHC Complexes in the π-Activation of Alkynes

Molecules, 2023
Silver–NHC (NHC = N-heterocyclic carbene) complexes play a special role in the field of transition-metal complexes due to (1) their prominent biological activity, and (2) their critical role as transfer reagents for the synthesis of metal-NHC complexes ...
Shiyi Yang, Tongliang Zhou, Xiang Yu, Michal Szostak   +3 more
doaj   +1 more source

Towards a Paradigm Shift in Polar Organometallic Chemistry

CHIMIA, 2020
Core tools of synthetic chemistry, polar organometallic reagents (typified by organolithium and Grignard reagents) are used worldwide for constructing compounds, especially aromatic compounds, which are ubiquitous in organic chemistry and thus in ...
Eva Hevia
doaj   +1 more source

Smart Ligands for Efficient 3d-, 4d- and 5d-Metal Single-Molecule Magnets and Single-Ion Magnets

Inorganics, 2020
There has been a renaissance in the interdisciplinary field of Molecular Magnetism since ~2000, due to the discovery of the impressive properties and potential applications of d- and f-metal Single-Molecule Magnets (SMMs) and Single-Ion Magnets (SIMs) or
Panagiota S. Perlepe, Diamantoula Maniaki, Evangelos Pilichos, Eugenia Katsoulakou, Spyros P. Perlepes   +4 more
doaj   +1 more source

Indenopyrans – synthesis and photoluminescence properties

Beilstein Journal of Organic Chemistry, 2016
New indeno[1,2-c]pyran-3-ones bearing different substituents at the pyran moiety were synthesized and their photophysical properties were investigated. In solution all compounds were found to be blue emitters and the trans isomers exhibited significantly
Andreea Petronela Diac, Ana-Maria Ţepeş, Albert Soran, Ion Grosu, Anamaria Terec, Jean Roncali, Elena Bogdan   +6 more
doaj   +1 more source

A Computational and Structural Database Study of the Metal-Carbene Bond in Groups IA, IIA, and IIIA Imidazol-2-Ylidene Complexes

Journal of Chemistry, 2019
Imidazol-2-ylidenes are important N-heterocyclic carbenes which have become universal ligands in organometallic and coordination chemistry. Generally classified as σ-donor ligands, these compounds have been used to stabilize various metal complexes which
Samuel Tetteh
doaj   +1 more source

Synthesis , Antibacterial Activity of Sm(III) Complex With L-phenylalanine

Zanco Journal of Pure and Applied Sciences, 2022
      Samarium–amino acid complex in aqueous solution was synthesized in formula:[Sm(phen)3].H2O, by reaction of  L-phenylalanine (phen) with samarium chloride hexahydrate (SmCl3.6H2O) in (1:3) M:L mole ratio .
Kamaran Basheer Hussein
doaj  

Asymmetric N-oxidation catalyzed by bisguanidinium dinuclear oxodiperoxomolybdosulfate

Nature Communications
N-oxides play a pivotal role in natural products and emerging drug design, while also serving as valuable ligand scaffolds in organometallic chemistry. Among heteroatom oxidations, the conversion of amines to N-oxides is a critical and challenging facet.
Wentao Wu, Esther Cai Xia Ang, Xinru Xu, Qi Wang, Hong Wang, Richmond Lee, Choon-Hong Tan, Xinyi Ye   +7 more
doaj   +1 more source

Intrinsically self-healing ethylene-anisylpropylene copolymer as a candidate material for innovative electrical insulation layers

Polymer Testing
A novel ethylene-anisylpropylene copolymer was tested as a candidate material for intrinsically self-healing electrical insulation layers. In addition to the thermal and mechanical properties, the dielectric properties were studied before and after ...
V. Nikolić, D. Háže, P. Kadlec, R. Polanský, M. Nishiura, Z. Hou   +5 more
doaj   +1 more source

Group IB organometallic chemistry. XXXII. Arylcopper compounds ArnCun as intermediates in organometallic synthesis. Single-step synthesis and dynamic NMR spectroscopy of diorganotin dihalides Ar2-nRnSnX2 (Ar 2-Me2NCH2C6H4 or (S)-2-Me2NCHMeC6H4; n 0 or 1)

, 1979
The selective, single-step synthesis of (2-Me2NCHZC6H4)RSnX2, in which Z H or Me, R Me or Ph and X Cl or Br, starting from the tetranuclear copper cluster compound (2-Me2NCHZC6H4)4Cu4 and RSnX3 is described. Reaction of (2-Me2NCH2C6H4)4Cu4 with SnBr4 in a 1/2 molar ratio afforded (2-Me2NCH2C6H4)2SnBr2 in almost quantitative yield.
Koten, G. van, Jastrzebski, J.T.B.H., Noltes, J.G.   +2 more
openaire   +3 more sources