Results 61 to 70 of about 31,892 (230)

Advances in Layered Double Hydroxide (LDH)-Based Materials for Electrocatalytic Nitrogen Reduction to Ammonia: A Comprehensive Review

Nitrogen
Nitrogen (N2), constituting the majority of Earth’s atmosphere, remains indispensable for biological systems and underpins modern agriculture and industry.
Sayali S. Kulkarni, Ganesh L. Khande, Jayavant L. Gunjakar, Valmiki B. Koli   +3 more
doaj   +1 more source

Tailored Catalytic Microenvironments Enable Efficient Electrochemical Ammonia Production

Advanced Science, EarlyView.
This study shows that Co2+ substitution in inverse spinel FeFeCoO4 constructs an integrated catalytic microenvironment for efficient nitrate‐to‐ammonia reduction. Jahn–Teller distortion activates Fe sites for *H generation, while hard–soft acid–base regulated dual‐metal sites optimize proton‐coupled electron transfer and intermediate adsorption ...
Qi Zhang, Peimiao Zou, Huimin Zhang, Alex J. Brown, Yingjie Song, Marc Walker, Yisong Han, Kui Xie, Shanwen Tao   +8 more
wiley   +1 more source

The Haber-Bosch Process in the Agro-Industrial Society: Dangers and Alternatives

, 2020
Pocas veces la ciencia y la política han tenido tanto en común como en el proceso Haber-Bosch. Esta síntesis industrial de nitrógeno es la base de la agroindustria y participa activamente de la industria de la guerra, entre otros renglones económicos ...
Estupiñan Silva, Rosmerlin, Quesada, Benjamín Raphael   +1 more
core   +1 more source

Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism

Nature Communications, 2018
The current industrial ammonia synthesis relies on the Haber-Bosch process that is limited by the Brønsted–Evans–Polanyi relation. Here, the authors propose a new strategy that an anchored Fe3 on θ-Al2O3(010) surface serves as a heterogeneous single ...
Jin-Cheng Liu, Xue-Lu Ma, Yong Li, Yang-Gang Wang, Hai Xiao, Jun Li   +5 more
doaj   +1 more source

Bioinspired Interfacial Hydration Engineering via Metal–Organic Frameworks for Efficient Nitrate‐To‐Ammonia Conversion in Neutral Media

Advanced Science, EarlyView.
Inspired by Nitrite reductase, a metal–organic framework overlayer is introduced to regulate the interfacial hydration microenvironment on Cu electrodes, enriching hydrated K+ species that act as efficient proton donors. This strategy enables nitrate‐to‐ammonia conversion with near‐unity selectivity at industrial‐level current densities in neutral ...
Yuyin Mao, Minghui Zhang, Xiangdong Xue, Chengyu Guo, Jian Liu   +4 more
wiley   +1 more source

Demagnetizing Ferromagnetic Catalysts to the Sabatier Op-timal of Haber-Bosch Process

, 2023
Achieving the Sabatier optimal of a chemical reaction has been the central topic in heterogenous catalysis for a century. However, this ultimate goal is greatly hindered by the extrinsic modifications in previous catalyst design strategies. Accord-ing to
Tao, Wang, Gaomou, Xu, Licheng, Sun
core   +1 more source

Interfacial Control in Cu–MXene Hybrids Enables Selective NOx‐to‐NH3 Electroconversion: A Critical Review

Advanced Science, EarlyView.
Cu‐MXene interfacial catalysts provide a promising platform for electrochemical NOx upcycling to ammonia. The synergy between Cu active sites and conductive, surface‐tunable MXene supports promotes NOx adsorption, intermediate stabilization, and selective NH3 formation while suppressing competing hydrogen evolution, offering a route toward sustainable ...
Hafiz Muhammad Adeel Sharif, Gechuanqi Pan, Yuwei Wang, Yasir Abbas, Asif Mahmood, Changping Li   +5 more
wiley   +1 more source

Computational Exploration of Adsorption Enhanced Haber-Bosch using MOFs and Ionic Liquid/MOFs

, 2021
In this work, molecular simulation is utilized to perform the adsorption based separation of the ammonia-hydrogen-nitrogen mixture on Metal-Organic Frameworks (MOFs) operating conditions relevant to enabling low-pressure Haber-Bosch.
Yusuf Bicer, Mohamed, Amro M. O.; id_orcid, Amro M.O. Mohamed, Bicer, Yusuf   +3 more
core   +1 more source

Catalytic Performance of Doped Ni₂P Surfaces for Ammonia Synthesis †

Engineering Proceedings, 2023
Ammonia is a key ingredient in fertilizer production, but its synthesis using the conventional Haber–Bosch process over metal-based catalysts is energy intensive.
Abdulrahman Almithn
doaj   +1 more source

Advancements in Graphdiyne‐Based Multiscale Catalysts for Green Hydrogen Energy Conversion

Advanced Intelligent Discovery, EarlyView.
This review systematically explores the fundamental characteristics of graphdiyne (GDY), cutting‐edge field of GDY‐based multiscale catalysts within sustainable energy conversion systems.Special emphasis is placed on the structure‒property relationships in different reactions.
Qian Xiao, Lu Qi, Siao Chen, Yurui Xue
wiley   +1 more source