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Synthetic approaches for thin-film halide double perovskites [PDF]
Summary Inspired by the fascinating class of hybrid organic-inorganic halide perovskite materials, halide double perovskites have emerged as non-toxic Pb-free contenders for application as active layers in optoelectronic devices. Heterovalent substitution of Pb2+ by non-toxic metal cations yields the double-perovskite structure, which allows for ...
Gerbrand Ceder +2 more
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Doubling the Stakes: The Promise of Halide Double Perovskites
Angewandte Chemie - International Edition, 2021AbstractWhen the stakes are doubled in a wager, a player must correctly place two consecutive bets to win, but the payout is larger. Similarly, two B sites in combination dictate the properties of A2BB′X6 (A=monocation, X=halide) double perovskites.
Nathan Wolf +2 more
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Small-Band-Gap Halide Double Perovskites
AbstractDespite their compositional versatility, most halide double perovskites feature large band gaps. Herein, we describe a strategy for achieving small band gaps in this family of materials. The new double perovskites Cs2AgTlX6 (X=Cl (1) and Br (2)) have direct band gaps of 2.0 and 0.95 eV, respectively, which are approximately 1 eV lower than ...
Jeffrey Neaton +2 more
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The Emergence of Halide Layered Double Perovskites [PDF]
Halide double perovskites have allowed the significant expansion of the possible metals and oxidation states in halide perovskites.
Diego Solis-Ibarra +2 more
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Progress of Lead-Free Halide Double Perovskites
Advanced Energy Materials, 2019AbstractThe field of halide metal perovskite photovoltaics has caught widespread interest in the last decade. This is seen in the rapid rise of power conversion efficiency, which is currently over 23%. It has also stimulated a widespread application of halide metal perovskites in other fields, such as light‐emitting diodes, field‐effect transistors ...
Femi Igbari +2 more
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Epitaxial Halide Perovskite Lateral Double Heterostructure
ACS Nano, 2017Epitaxial III-V semiconductor heterostructures are key components in modern microelectronics, electro-optics, and optoelectronics. With superior semiconducting properties, halide perovskite materials are rising as promising candidates for coherent heterostructure devices. In this report, spinodal decomposition is proposed and experimentally implemented
Yiping Wang +7 more
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Unique Behavior of Halide Double Perovskites with Mixed Halogens
ACS Applied Materials & Interfaces, 2020Engineering halide double perovskite (A2M+M3+XVII6) by mixing elements is a viable way to tune its electronic and optical properties. In spite of many emerging experiments on halide double perovskite alloys, the basic electronic properties of the alloys have not been fully understood.
Dan Han +3 more
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Rational Design of Halide Double Perovskites for Optoelectronic Applications [PDF]
Summary Practical application of hybrid Pb-based halide perovskites needs not only to fabricate high-quality film samples on a large scale but also to properly overcome the issues of Pb toxicity and materials instability. Finding new, stable, Pb-free perovskites currently attracts significant research interest.
Lijun Zhang, Xin-Gang Zhao, Zewen Xiao
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