Results 231 to 240 of about 78,220 (312)

(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications

open access: yesAngewandte Chemie, EarlyView.
In this review, we spotlight recent breakthroughs in α‐polyboron‐substituted carbon‐centered intermediates (carbanion, carbocation, radical, and carbene) and polyborylated alkenes. By bridging fundamental reactivity with the application potential of these extraordinary species, we hope this review will serve as a roadmap for harnessing these unique ...
Nadim Eghbarieh   +5 more
wiley   +1 more source

Tailoring a Lead-Free Organic-Inorganic Halobismuthate for Large Piezoelectric Effect. [PDF]

open access: yesJ Am Chem Soc
Hung EYH   +15 more
europepmc   +1 more source

Halide Bond Assisted Double Desymmetrization of Meso‐Dicarboxylic Acids with Symmetrical Olefins via Asymmetric Halogenation

open access: yesAngewandte Chemie, EarlyView.
This work demonstrates a double desymmetrization of meso‐dicarboxylic acids with symmetrical olefins, constructing complex chiral lactones with six stereocenters in one step. Unexpectedly, the halide bond was found to be crucial in achieving high stereoselectivity.
Qingyu Zhang   +3 more
wiley   +1 more source

One‐Pot Incorporation of Quantum Defects into Single‐Walled Carbon Nanotubes with Arylazo Sulfonates

open access: yesAngewandte Chemie, EarlyView.
We present a photochemical strategy to create complex aromatic quantum defects in carbon nanotubes using arylazo sulfonates. It provides access to brighter carbon nanotubes without purification and simpler biofunctionalization. Abstract Single‐walled carbon nanotubes (SWCNTs) consist of a carbon monolayer and fluoresce in the near‐infrared (NIR, 800 ...
Valeriia D. Andreeva   +4 more
wiley   +1 more source

Dispersion‐Enhanced Nitrogen‐Centered Photocatalysis of the Direct Hydrogen Atom Transfer

open access: yesAngewandte Chemie, EarlyView.
Nitrogen‐centered acridine photocatalysts for direct hydrogen atom transfer have been developed, leveraging dispersion interactions to enhance photocatalytic activity. This approach enables diverse functionalization reactions of strong C─H bonds even under cryogenic conditions and provides a new strategy for boosting the efficiency of direct HAT ...
Jiasong Zhang   +16 more
wiley   +1 more source

Exploring non-covalent interactions in binary aromatic complexes.

open access: yesCrystEngComm
Bear JC   +3 more
europepmc   +1 more source

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