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Halogen bonding: Recent advances

Current Opinion in Solid State and Materials Science, 2009
Halogen bonding (XB), as a directional interaction between covalently bound halogen atoms (XB donor) and Lewis bases (A, XB acceptor), has been recently intensively investigated as a powerful tool in crystal engineering. After a short review on the origin and general features of halogen bonding, current developments towards (i) the elaboration of three-
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The Halogen Bond: An Emerging Supramolecular Tool in the Design of Functional Mesomorphic Materials.

Chemistry, 2018
Owing to their dynamic attributes, non-covalent supramolecular interactions have enabled a new paradigm in the design and fabrication of multifunctional material systems with programmable properties, performances, and reconfigurable traits. Recently, the
Hao Wang   +4 more
semanticscholar   +1 more source

Halogen-bond-assisted radical activation of glycosyl donors enables mild and stereoconvergent 1,2-cis-glycosylation

Nature Chemistry, 2022
Chen Zhang   +6 more
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Selective Emergence of the Halogen Bond in Ground and Excited States of Noble-Gas-Chlorine Systems.

Angewandte Chemie, 2019
Molecular-beam scattering experiments and theoretical calculations prove the nature, strength, and selectivity of the halogen bonds (XB) in the interaction of halogen molecules with the series of noble gas (Ng) atoms.
F. Pirani   +6 more
semanticscholar   +1 more source

Halogen Bonding Defined

Chemical & Engineering News Archive, 2012
Halogen bonding, akin to hydrogen bonding, is a noncovalent interaction between a positive region on a halogen atom and a negative site, such as a lone pair on a nitrogen or oxygen. Following on the heels of a new definition for hydrogen bonding, an International Union of Pure & Applied Chemistry (IUPAC) committee has now proposed a definition for ...
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Visualizing halogen bonding

Science, 2017
Surface Chemistry Even though halogen atoms are highly electronegative, a noncovalent bond can form between an electron donor and a halogen atom in a covalent bond. Such interactions are facilitated by the formation of electron-depleted regions in the halogen's covalent bond, a situation least likely for fluorine atoms. Han et al.
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Studies in halogen-halogen bonding

Theoretica Chimica Acta, 1970
G. H. Cheesman   +2 more
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