Halogen Bonding in Crystal Engineering [PDF]
Acta Crystallographica Section A Foundations of Crystallography, 2005 The term halogen bonding encompasses any non-covalent interaction involving halogens as electrophilic species. High strength and directionality are the remarkable features of halogen bonding that fully justify its use as a primary intermolecular interaction to dictate molecular self-assembly processes.
METRANGOLO, PIERANGELO +3 more
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Photoswitching Conduction in Framework Materials
Advanced Functional Materials, EarlyView.This mini‐review summarizes recent advances in state‐of‐the‐art proton and electron conduction in framework materials that can be remotely and reversibly switched on and off by light. It discusses the various photoswitching conduction mechanisms and the strategies employed to enhance photoswitched conductivity.
Helmy Pacheco Hernandez +4 more
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Effects of Linker Structures in Designing Perfluoroiodobenzene- Based Halogen-Bond Donor Catalysts with Two-Point Activation Modes [PDF]
, 2023 Masayuki KATO +8 more
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Halogen bonding regulated functional nanomaterials
Nanoscale Advances, 2021 Herein, the latest development of XB as a flexible linkage to fabricate functional nanomaterials in liquid and solution phases will be discussed, taking readers through the concept and features of XB to explore its functionalities and applications.
Jie Zheng +4 more
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Biomimetic Iridescent Skin: Robust Prototissues Spontaneously Assembled from Photonic Protocells
Advanced Functional Materials, EarlyView.Uniform nanoparticles are induced to form arrays (photonic crystals) in the cores of biopolymer capsules, endowing these ‘protocells’ with structural color. These protocells are then assembled into large self‐standing objects, i.e., prototissues, with robust mechanical properties as well as iridescent optical properties.
Medha Rath +6 more
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Strength of the [Z–I···Hal]− and [Z–Hal···I]− Halogen Bonds: Electron Density Properties and Halogen Bond Length as Estimators of Interaction Energy [PDF]
, 2021 Maxim L. Kuznetsov
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MOFs and COFs in Electronics: Bridging the Gap between Intrinsic Properties and Measured Performance
Advanced Functional Materials, EarlyView.Metal‐organic frameworks (MOFs) and covalent organic frameworks (COFs) hold promise for advanced electronics. However, discrepancies in reported electrical conductivities highlight the importance of measurement methodologies. This review explores intrinsic charge transport mechanisms and extrinsic factors influencing performance, and critically ...
Jonas F. Pöhls, R. Thomas Weitz
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New Type of Halogen Bond: Multivalent Halogen Interacting with π- and σ-Electrons
Molecules, 2017 MP2/aug-cc-pVTZ calculations were performed for complexes of BrF3 and BrF5 acting as Lewis acids through the bromine centre, with species playing a role of Lewis base: dihydrogen, acetylene, ethylene, and benzene. The molecular hydrogen donates electrons
Sławomir J. Grabowski
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Anion Recognition by Neutral and Cationic Iodotriazole Halogen Bonding Scaffolds
Molecules, 2020 A computational study of the iodide discrimination by different neutral and cationic iodotriazole halogen bonding hosts was carried out by means of Density Functional Theory.
Iñigo Iribarren +2 more
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Ice Lithography: Recent Progress Opens a New Frontier of Opportunities
Advanced Functional Materials, EarlyView.This review focuses on recent advancements in ice lithography, including breakthroughs in compatible precursors and substrates, processes and applications, hardware, and digital methods. Moreover, it offers a roadmap to uncover innovation opportunities for ice lithography in fields such as biological, nanoengineering and microsystems, biophysics and ...
Bingdong Chang +9 more
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