Asymmetric Counteranion-Directed Halogen Bonding Catalysis. [PDF]
Reinhard DL +6 more
europepmc +1 more source
Investigation of the Effect of Solvents on the Synthesis of Aza-flavanone from Aminochalcone Facilitated by Halogen Bonding. [PDF]
Maharana RR, Bhanja R, Mal P, Samanta K.
europepmc +1 more source
Sulfur‐Boron Lewis Pair‐Catalyzed Hydrohalogenation of Alkynes via Formal Hydrogen Atom Transfer
A sulfur‐boron Lewis pair enables the stereodivergent hydrohalogenation of alkynes with exclusive Markovnikov selectivity. Mechanistic studies support a proton transfer‐electron transfer (PT‐ET) sequence for vinyl radical formation rather than a concerted hydrogen atom transfer (HAT) pathway.
Yun Soo Shim +4 more
wiley +2 more sources
Chloride Selective, Nonprotonophoric Ion Transport with Macrocyclic Halogen Bonding Anionophores. [PDF]
Flerin M, Duarte F, Langton MJ.
europepmc +1 more source
Halogen bonding-guided growth of heteroatom-rich polycarbazole wires on Au(111). [PDF]
Palmino F +4 more
europepmc +1 more source
Synthesis, Structure, and Reactivity of Hypervalent Iodine Reagents Stabilized by Internal Out-of-Plane Halogen Bonding: <i>ortho-</i>Bromo and <i>ortho-</i>Chloro-Substituted [Hydroxy(tosyloxy)iodo]arenes and Iodonium Ylides. [PDF]
Zarrabi N +7 more
europepmc +1 more source
Modular access to underexplored C5‐sulfenyl thiazoles via an intermolecular Pummerer rearrangement is reported. The methodology exhibits a broad functional group tolerance enabling the seamless design of trisubstituted thiazole cores bearing a sulfur handle for further elaboration.
Joe L. Smy +5 more
wiley +1 more source
Halogen Bonding and Rearrangements in Complexes of N-Chlorosuccinimide with Halides. [PDF]
Hardin M, Zeller M, Rosokha SV.
europepmc +1 more source
One catalyst for two products: CO acts as a molecular trigger for adaptive alkyne hydrogenation using supported Pd nanoparticles. The catalyst reversibly switches between the formation of alkanes under H2 and Z‐alkenes under H2/CO for 37 structurally diverse alkynes.
Manisha Durai +7 more
wiley +1 more source
Dual Semiconductor-Photoredox/Halogen-Bonding Organocatalyzed Cascade Sulfonylation/Cyclization of Alkynes and Alkenes with RSO<sub>2</sub>Cl. [PDF]
Wang YH +7 more
europepmc +1 more source

