Results 141 to 150 of about 16,385 (196)

Asymmetric Counteranion-Directed Halogen Bonding Catalysis. [PDF]

open access: yesJ Am Chem Soc
Reinhard DL   +6 more
europepmc   +1 more source

Sulfur‐Boron Lewis Pair‐Catalyzed Hydrohalogenation of Alkynes via Formal Hydrogen Atom Transfer

open access: yesAngewandte Chemie, EarlyView.
A sulfur‐boron Lewis pair enables the stereodivergent hydrohalogenation of alkynes with exclusive Markovnikov selectivity. Mechanistic studies support a proton transfer‐electron transfer (PT‐ET) sequence for vinyl radical formation rather than a concerted hydrogen atom transfer (HAT) pathway.
Yun Soo Shim   +4 more
wiley   +2 more sources

Halogen bonding-guided growth of heteroatom-rich polycarbazole wires on Au(111). [PDF]

open access: yesNanoscale Adv
Palmino F   +4 more
europepmc   +1 more source

A Modular Synthesis of C5‐Sulfenyl Thiazoles via an Intermolecular Pummerer Rearrangement: An Underexplored Scaffold for Medicinal Chemistry

open access: yesAngewandte Chemie, EarlyView.
Modular access to underexplored C5‐sulfenyl thiazoles via an intermolecular Pummerer rearrangement is reported. The methodology exhibits a broad functional group tolerance enabling the seamless design of trisubstituted thiazole cores bearing a sulfur handle for further elaboration.
Joe L. Smy   +5 more
wiley   +1 more source

Adaptive Hydrogenation of Alkynes Using CO as a Molecular Trigger to Selectively Produce Alkanes or Z‐Alkenes

open access: yesAngewandte Chemie, EarlyView.
One catalyst for two products: CO acts as a molecular trigger for adaptive alkyne hydrogenation using supported Pd nanoparticles. The catalyst reversibly switches between the formation of alkanes under H2 and Z‐alkenes under H2/CO for 37 structurally diverse alkynes.
Manisha Durai   +7 more
wiley   +1 more source

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