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Pharmaceuticals Made with Hydrogen: A Sustainable and Efficient Approach Using Flow Synthesis
Chemistry – A European Journal, EarlyView.We demonstrate a sustainable strategy for pharmaceutical manufacturing by combining hydrogen, heterogeneous catalysis, and continuous flow synthesis. The development of novel catalysts and their application in a multi‐step synthesis of donepezil enabled a highly productive process with no intermediate purification.
Shū Kobayashi, Haruro Ishitani
wiley +1 more source
Chemistry – A European Journal, EarlyView.A self‐assembled hydrophobic and red phosphorescent Au(I) coordination polymer (CP) was synthesized under mild conditions. Single‐crystal X‐ray diffraction (XRD) demonstrated linear Au(I) chains stabilized by aurophilic and hydrogen bonding interactions.
Miguel Justo‐Tirado +4 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.ABSTRACT In the field of organoboron chemistry, multi(boronate) esters have emerged as crucial intermediates, with various applications in synthetic chemistry, material technology, and life sciences. This mini‐review discusses recent advancement in the synthesis of these versatile compounds, particularly alkynylboronates, 1,1‐diborylalkenes, and 1,1,1 ...
Son Hoai Doan +2 more
wiley +1 more source
Combination of Hydrogen and Halogen Bonds in the Crystal Structures of 5-Halogeno-1H-isatin-3-oximes: Involvement of the Oxime Functionality in Halogen Bonding. [PDF]
MoleculesMeier E, Seichter W, Mazik M.
europepmc +1 more source
Hybrid 2D Supramolecular Organic Frameworks (SOFs) Assembled by the Cooperative Action of Hydrogen and Halogen Bonding and π⋯π Stacking Interactions. [PDF]
Int J Mol SciBaykov SV +7 more
europepmc +1 more source
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Halogen Bonding in Supramolecular Chemistry
Angewandte Chemie - International Edition, 2008AbstractHalogen bonding is the noncovalent interaction where halogen atoms function as electrophilic species. The energetic and geometrical features of the interaction are described along with the atomic characteristics that confer molecules with the specific ability to interact through this interaction.
Pierangelo Metrangolo +2 more
exaly +7 more sources
Halogen Bonding Molecular Capsules
Angewandte Chemie - International Edition, 2015AbstractMolecular capsules based solely on the interaction of halogen bonding (XB) are presented along with their host–guest binding properties in solution. The first example of a well‐defined four‐point XB supramolecular system is realized by decorating resorcin[4]arene cavitands with polarized halogen atoms for dimerization with tetra(4‐pyridyl ...
Oliver Dumele +2 more
exaly +4 more sources
Halogen Bonding: An Interim Discussion
ChemPhysChem, 2013AbstractHalogen bonding is a noncovalent interaction that is receiving rapidly increasing attention because of its significance in biological systems and its importance in the design of new materials in a variety of areas, for example, electronics, nonlinear optical activity, and pharmaceuticals.
Peter Politzer, Jane S Murray
exaly +3 more sources
Halogen bond-induced electrophilic aromatic halogenations
Organic & Biomolecular Chemistry, 2021This review highlights the recent development of halogen bond-induced activations of N-halosuccinimides and N,N-dihalodimethylhydantoins in electrophilic aromatic halogenations.
Wanutcha Lorpaiboon, Pakorn Bovonsombat
openaire +2 more sources