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Carbon and Hydrogen, EarlyView.This review systematically summarizes research progress on bismuth‐based semiconductor photocatalytic materials in the field of CO2 reduction. It focuses on elucidating the mechanisms by which four modification strategies—including heteroatom doping, oxygen vacancy engineering, microstructural control, and heterostructure fabrication—regulate band ...
Shuisen He +6 more
wiley +1 more source
Combination of Hydrogen and Halogen Bonds in the Crystal Structures of 5-Halogeno-1H-isatin-3-oximes: Involvement of the Oxime Functionality in Halogen Bonding. [PDF]
MoleculesMeier E, Seichter W, Mazik M.
europepmc +1 more source
Activation of a Metal‐Halogen Bond by Halogen Bonding [PDF]
Angewandte Chemie - International Edition, 2020 In recent years, the non-covalent interaction of halogen bonding (XB) has found increasing application in organocatalysis. However, reports of the activation of metal-ligand bonds by XB have so far been limited to a few reactions with elemental iodine or
Claude Legault +2 more
exaly +11 more sources
“Anti‐Electrostatic” Halogen Bonding [PDF]
Angewandte Chemie - International Edition, 2020 Halogen bonding (XB) is often described as being driven predominantly by electrostatics, and thus adducts between anionic XB donors (halogen-based Lewis acids) and anions seem counterintuitive.
Stefan M Huber, Elric Engelage
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Halogen Bonding in Supramolecular Chemistry [PDF]
Angewandte Chemie - International Edition, 2008 Halogen bonding (XB) is the noncovalent interaction where halogen atoms function as electrophilic species. The energetic and geometrical features of the interaction are described along with the atomic characteristics conferring to molecules the specific ...
Giuseppe Resnati +2 more
exaly +8 more sources
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Halogen bond-induced electrophilic aromatic halogenations
Organic & Biomolecular Chemistry, 2021This review highlights the recent development of halogen bond-induced activations of N-halosuccinimides and N,N-dihalodimethylhydantoins in electrophilic aromatic halogenations.
Wanutcha Lorpaiboon, Pakorn Bovonsombat
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Chemical Society Reviews, 2012
Halogen bonding is the electron density donation based weak interaction of halogens with Lewis bases. Its applicability for molecular recognition processes long remained unappreciated and has so far mostly been studied in silico and in solid state.
Erdelyi, M.
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Halogen bonding is the electron density donation based weak interaction of halogens with Lewis bases. Its applicability for molecular recognition processes long remained unappreciated and has so far mostly been studied in silico and in solid state.
Erdelyi, M.
openaire +2 more sources
On The Nature of the Halogen Bond
Journal of Chemical Theory and Computation, 2014The wide-ranging applications of the halogen bond (X-bond), notably in self-assembling materials and medicinal chemistry, have placed this weak intermolecular interaction in a center of great deal of attention. There is a need to elucidate the physical nature of the halogen bond for better understanding of its similarity and differences vis-à-vis other
Changwei, Wang +3 more
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On the directionality of halogen bonding
Physical Chemistry Chemical Physics, 2013The origin of the high directionality of halogen bonding was investigated quantum chemically by a detailed comparison of typical adducts in two different orientations: linear (most stable) and perpendicular. Energy decomposition analyses revealed that the synergy between charge-transfer interactions and Pauli repulsion are the driving forces for the ...
Stefan M, Huber +4 more
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