Fullerene-Functionalized Halogen-Bonding Heteroditopic Hosts for Ion-Pair Recognition. [PDF]
J Am Chem Soc, 2023 Despite their hydrophobic surfaces with localized π-holes and rigid well-defined architectures providing a scaffold for preorganizing binding motifs, fullerenes remain unexplored as potential supramolecular host platforms for the recognition of anions ...
Bąk KM +5 more
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Halogen-bonding-promoted Photo-induced C–X Borylation of Aryl Halide using Phenol Derivatives [PDF]
, 2022 This study investigates the photo-induced C–X borylation reaction of aryl halides by forming a halogen-bonding complex. The method employs 2-naphthol as a halogen-bonding acceptor and proceeds under mild conditions without a photoredox catalyst under 420
Eiji, Yamaguchi +2 more
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Redox-Modulated Fluorescent Halogen Bonding and Hydrogen Bonding Anion Sensing [PDF]
, 2023 Anion sensing via either optical or electrochemical readouts has separately received enormous attention, however a judicious combination of the advantages of both modalities remains almost entirely unexplored. Toward this goal we herein disclose a series
Paul D., Beer +4 more
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Mechanical Bond Enhanced Lithium Halide Ion-Pair Binding by Halogen Bonding Heteroditopic Rotaxanes [PDF]
, 2022 A family of novel halogen bonding (XB) and hydrogen bonding (HB) heteroditopic [2]rotaxane host systems constructed by active metal template (AMT) methodology, were studied for their ability to cooperatively recognise lithium halide (LiX) ion-pairs.
Dilhan, Manawadu +4 more
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Promoting Halogen-Bonding Catalyzed Living Radical Polymerization through Ion-Pair Strain [PDF]
, 2022 Discovering efficient catalysts is highly desired in expanding the application of halogen-bonding catalysis. We herein report our findings on applying triaminocyclopropenium (TAC) iodides as highly potent catalysts for halogen-bonding catalyzed living ...
Yiliu, Liu +4 more
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Type II halogen···halogen contacts are halogen bonds [PDF]
IUCrJ, 2013 Cl/Br/I alternative substitutions in a series of dihalophenols indicate that type I and type II halogen···halogen contacts have different chemical nature. Only the latter ones qualify as true halogen bonds, according to the recent IUPAC definition.
METRANGOLO, PIERANGELO +1 more
openaire +4 more sources
Cooperativity of halogen bonds – enhancing halogen-bond donating ability of halogenated pyridines through halogen bonding with N-haloimides [PDF]
Acta Crystallographica Section A Foundations and Advances, 2018 N-halogenated imides, common halogenating agents in organic synthesis, have recently been marked as extremely strong halogen donors. In previous studies we have demonstrated that N-halogenated succinimides form extremely short XBs with halogen bond energies between 20 and 60 kJ mol–1, depending on the pyridine basicity and the halogen atom. In light of
Stilinović, Vladimir, Cinčić, Dominik
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Virtual Issue on Halogen Bonding [PDF]
, 2022 Despite its identification in the early 19th century, the fundamental understanding of halogen bonding continues to hold immense interest in crystal engineering and supramolecular chemistry.
Mahesh Hariharan, Hariharan, Mahesh
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Halogen Bonding in N-Alkyl-3-halogenopyridinium Salts
Crystals, 2021 We performed a structural study of N-alkylated halogenopyridinium cations to examine whether choice of the N-substituent has any considerable effect on the halogen bonding capability of the cations.
Luka Fotović, Vladimir Stilinović
doaj +1 more source
Realizing Two-Dimensional Spin Arrays on Surfaces via Halogen-Bonding Molecular Self-Assembly [PDF]
, 2021 Well-ordered spin arrays are highly desirable for next-generation molecule-based magnetic devices, and yet its synthetic method remains a challenging task.
Dingguan, Wang +8 more
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