Results 181 to 190 of about 469,475 (238)

Supramolecular Enforcement of Planar Tetracoordinate Halides

Angewandte Chemie, EarlyView.
A calix[4]pyrrolato‐indium scaffold preorganizes Li4 pockets that trap Cl−, Br−, and I− in strongly flattened to square‐planar tetracoordinate environments. Computations reveal low planarization energies for the heavier halides, while crystallography shows that their geometry is readily modulated by subtle supramolecular and packing effects ...
Jie Zhang, Avijit Maiti, Lutz Greb
wiley   +2 more sources

Mortise-Tenon Joint Inspired Weakly Solvated Gel Electrolyte Based on Halogen Bonds for High-Voltage Lithium Metal Batteries. [PDF]

Adv Sci (Weinh)
Liu S, Tian W, Pan H, Chen S, Han X, Quan H, Zhu S.   +6 more
europepmc   +1 more source

Potent DNA gyrase inhibitors bind asymmetrically to their target using symmetrical bifurcated halogen bonds. [PDF]

Nat Commun, 2021
Kolarič A, Germe T, Hrast M, Stevenson CEM, Lawson DM, Burton NP, Vörös J, Maxwell A, Minovski N, Anderluh M.   +9 more
europepmc   +1 more source

Tunable Raman Scattering of Fe(II) Coordination Networks With Magnetic Fields

Angewandte Chemie, EarlyView.
Four heavy Hg(II) coordination networks with paramagnetic Fe(II) sites reveal strong and halogen‐tunable low‐frequency (LF) sub‐terahertz phonons and field‐dependent magnetic transitions. LF phonon spectroscopy and Raman magnetospectroscopy are powerful probes of structure, low‐energy vibration, zero‐field splitting, and spin–phonon coupling supported ...
Guanping Li, Olaf Stefanczyk, Joseph M. Flitcroft, Jonathan M. Skelton, William T. Morrillo, Meagan Oakley, Lulu Xiong, Koji Nakabayashi, Dmitry Smirnov, Komalavalli Thirunavukkuarasu, Mykhaylo Ozerov, Shin‐ichi Ohkoshi, Nicholas F. Chilton   +12 more
wiley   +2 more sources

Unveiled Impact of ²¹¹At-Labeled Compounds' Ability to Form Halogen Bonds on Their <i>In Vivo</i> Stability. [PDF]

ACS Phys Chem Au
Mador SD, Yssartier T, Le Questel JY, Montavon G, Guérard F, Galland N.   +5 more
europepmc   +1 more source

Extension of an Atom-Atom Dispersion Function to Halogen Bonds and Its Use for Rational Design of Drugs and Biocatalysts. [PDF]

J Phys Chem A, 2021
Jedwabny W, Dyguda-Kazimierowicz E, Pernal K, Szalewicz K, Patkowski K.   +4 more
europepmc   +1 more source

Chalcogen-Bonded [Se-N]₂ Cyclic Supramolecular Synthons Enhanced by Halogen Bonds: Studies in the Gas Phase and Crystalline Phase. [PDF]

Int J Mol Sci
Miao S, Sun X, Zhang Y, Wang W.
europepmc   +1 more source

Halogen Bonds of Halogen(I) Ions─Where Are We and Where to Go? [PDF]

J Am Chem Soc
Wieske LHE, Erdelyi M.
europepmc   +1 more source

Catalyst‐Controlled Divergent Strain‐Release Amination and Skeletal Remodeling of Bicyclo[1.1.0]Butanes

Angewandte Chemie, EarlyView.
Catalyst‐controlled nitrene transfer unlocks divergent reactivity of bicyclo[1.1.0]butanes. Rhodium catalysis promotes selective strain‐release amination to access cyclobutene and cyclobutane amino‐acid scaffolds, whereas visible‐light photocatalysis redirects nitrene reactivity toward double amination and skeletal remodeling, providing a complementary
Aksar Ali, Lennard Kloene, Justus Koedel, Yifan Guo, Minakshi Altia, Rene M. Koenigs   +5 more
wiley   +2 more sources

Interplay of Tetrel, Hydrogen, and Halogen Bonds in F₃GeOCl and HCN Complexes: A Comprehensive Theoretical Study of Dimers, Trimers, and Tetramers. [PDF]

J Phys Chem A
Frontera A, Emamian S.
europepmc   +1 more source