Results 81 to 90 of about 469,475 (238)
Rigid Boron‐Fused Frameworks for Efficient Near‐Infrared Emission and Optical Gain Beyond 900 nm
Advanced Optical Materials, EarlyView.Multiple‐resonance (MR)‐derived boron‐fused frameworks were integrated into narrow‐gap, long‐range charge‐transfer emitters to reduce structural relaxation and electron‐vibrational coupling. This strategy significantly decreases nonradiative losses, leading to improved near‐infrared (NIR) luminescence efficiency and low‐threshold amplified spontaneous ...
Masashi Mamada +6 more
wiley +1 more source
Acta Crystallographica Section E: Crystallographic Communications, 2015 The crystallization of a 1:1 molar solution of 1,2-diiodo-3,4,5,6-tetrafluorobenzene (o-DITFB) and tetrabutylammonium bromide (n-Bu4NBr) from dichloromethane yielded pure white crystals of a halogen-bonded compound, C16H36N+·Br−·C6F4I2·0.5CH2Cl2 or [(n ...
Jasmine Viger-Gravel +2 more
doaj +1 more source
Can Halogen Clusters be Emissive? [PDF]
, 2020 Halogen-halogen short contacts, especially halogen bonds (XBs) have been widely utilized in multifarious fields, owing to its bridging function among luminophores as well as well-known heavy atom effect.
Wang Zhang, Yuan +5 more
core +2 more sources
Degradable Magnetic Composites from Recycled NdFeB Magnets for Soft Actuation and Sensing
Advanced Robotics Research, EarlyView.This work presents a degradable soft magnetic composite made from recycled NdFeB particles embedded in a gelatin‐based organogel. The material is processed into magnetic sensors and soft robotic components, which can later be dissolved in a green solvent to recover NdFeB magnetic particles.
Muhammad Bilal Khan +14 more
wiley +1 more source
Structural Competition between Hydrogen Bonds and Halogen Bonds
, 2016 The molecules presented here provide a test-bed for competitive supramolecular chemistry, and on the basis of five crystal structures a ranking of the relative structural importance and influence of competing weak/strong hydrogen bonds and weak/strong ...
Meg Fasulo (2162293) +4 more
core +2 more sources
Machine Learning for Green Solvents: Assessment, Selection and Substitution
Advanced Science, EarlyView.Environmental regulations have intensified demand for green solvents, but discovery is limited by Solvent Selection Guides (SSGs) that quantify solvent sustainability. Training a machine learning model on GlaxoSmithKline SSG, a database of sustainability metrics for 10,189 solvents, GreenSolventDB is developed. Integrated with Hansen solubility metrics,
Rohan Datta +4 more
wiley +1 more source
Metal Hydrides Form Halogen Bonds: Measurement of Energetics of Binding
, 2015 : The formation of halogen bonds from iodopentafluorobenzene and 1-iodoperfluorohexane to a series of bis(η5-cyclopentadienyl)metal ...
Dan A. Smith +7 more
core +1 more source
Orthogonal halogen and hydrogen bonds involving a peptide bond model [PDF]
, 2014 The peptide bond model N-methylacetamide self-assembles with a range of dihalotetrafluorobenzenes forming co-crystals that all show the occurrence of orthogonal hydrogen and halogen ...
RESNATI, GIUSEPPE +7 more
core +1 more source
Advanced Science, EarlyView.Fluorescent BODIPY‐conjugated thiosemicarbazone ligands and their Ga(III), In(III), and Fe(III) complexes, inspired by Triapine, are developed as theranostic agents. Multiphoton FLIM and confocal microscopy in cancer cells and zebrafish reveal real‐time uptake, mitochondrial localisation, and whilst spectroscopic assays indicated preserved complex ...
Megan J. Green +15 more
wiley +1 more source
Advanced Science, EarlyView.Glaucoma, a major cause of blindness, involves retinal ganglion cell (RGC) degeneration. This study shows growth hormone‐releasing hormone receptor (GHRHR) deficiency preserves RGC survival and restores vision, unlike activation which only aids survival.
Yan Tong +24 more
wiley +1 more source