Results 81 to 90 of about 12,869 (241)

Halogenated Tryptophans Improve Integrin αVβ6 Affinity of Cyclic RGD Peptides and Provide Handles for Late‐Stage Derivatization

open access: yesChemistry – A European Journal, EarlyView.
Lighting up αVβ6: Halotryptophan engineering converts an RGD scaffold into a modular αVβ6 ligand platform, enabling picomolar affinity and late‐stage functionalization. The resulting probes combine high selectivity with fluorescence for FACS and tumor imaging.
Beate Nachtigall   +4 more
wiley   +1 more source

Photostability of Cyanine Dyes and Its Correlation to Their Photothermal and Photodynamic Effects

open access: yesChemistry – A European Journal, EarlyView.
Photostability (PS) of dyes is a crucial parameter for performance in biological applications, yet often underrated. Here PS of several cyanines is investigated. The method is carefully evaluated and designed as a general and easy tool to compare PS of NIR dyes.
Clara Schäfer, Bo W. Laursen
wiley   +1 more source

Dichlorinated and Brominated Rugulovasines, Ergot Alkaloids Produced by Talaromyces wortmannii

open access: yesMolecules, 2015
UHPLC-DAD-HRMS based dereplication guided the detection of new halogenated alkaloids co-produced by Talaromyces wortmannii. From the fungal growth in large scale, the epimers 2,8-dichlororugulovasines A and B were purified and further identified by means
Lívia Soman de Medeiros   +9 more
doaj   +1 more source

Designing Threefold π‐Surfaces Through Peripheral Halogenation to Shape Multidirectional Molecular Packing

open access: yesChemistry – A European Journal, EarlyView.
The complete series of hexahalogenated triptycene‐tribenzoquinones, comprising newly synthesized fluoro‐, bromo‐, and iodo‐substituted derivatives together with the previously reported chloro analogue, enables systematic comparison of their molecular properties and intermolecular interactions in relation to their crystal packing modes.
Shuta Tsuruga   +4 more
wiley   +1 more source

Disinfection by-products from halogenation of aqueous solutions of terpenoids [PDF]

open access: yes, 2010
We report the formation of trihalomethanes and other disinfection by-products from four polyfunctional terpenoids during simulated chlorination of natural waters.
Heitz, Anna   +2 more
core   +2 more sources

Next‐Generation Carbon‐Based Anodes for Alkali Metal‐Ion Batteries: Recent Progress on Biphenylene and Emerging Materials

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Recent advances in carbon‐based anodes for alkali metal‐ion batteries are critically reviewed, with emphasis on biphenylene and other emerging carbon allotropes. Biphenylene exhibits exceptional theoretical electrochemical properties beyond conventional graphite, highlighting its strong potential as a next‐generation anode material once scalable ...
Adewale Hammed Pasanaje, Nirpendra Singh
wiley   +1 more source

Asymmetric Synthesis of Tertiary α‐Aryl Stereocentres in Tetrahydro‐4H‐pyran‐4‐ones Using Pd‐Catalyzed Decarboxylative Asymmetric Protonation

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The Pd‐catalyzed decarboxylative asymmetric protonation (DAP) has been developed for sterically hindered tetrahydro‐4H‐pyran‐4‐one derived α‐aryl‐β‐keto esters. A substrate scope of nine examples of DAP showed that substrates containing a di‐ortho methoxy substitution pattern on the aryl ring gave rise to the highest enantioselectivities of up to 85 ...
Fionn McNeill   +5 more
wiley   +1 more source

Resolution Approaches Toward Enantiopure Planar Chiral 7‐bromo‐4‐hydroxy [2.2]paracyclophane

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This work describes access to both enantiomers of planar chiral 7‐bromo‐4‐hydroxy [2.2]paracyclophane through direct resolution of the racemate using an L‐isoleucine‐derived chiral auxiliary or through resolution of 4‐hydroxy [2.2]paracyclophane, followed by regioselective bromination.
Arthur Le Coz   +5 more
wiley   +1 more source

Halogenated Tryptophan Derivatives by Enzymatic Halogenation

open access: yes, 2022
Besse C, Sewald N. Halogenated Tryptophan Derivatives by Enzymatic Halogenation. In: Journal of Peptide Science. Vol 28.
Besse, Caroline   +1 more
core  

Counterion Effects in Decatungstate Photocatalysis

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Decatungstate photocatalysis is often discussed from an anion‐centered perspective, treating the counterion as a passive charge‐balancing species. This review highlights that counterion identity can instead profoundly influence catalyst solubility, ion pairing, aggregation, stability, substrate accessibility, and catalytic performance.
Florence Babawale   +2 more
wiley   +1 more source

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