Results 81 to 90 of about 7,389 (151)

Late‐Stage Functionalization of Peptides on the Solid Phase

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 31, 27 July 2026.
Peptide modifications are essential to control pharmacodynamic and pharmacokinetic properties of peptide drugs. Consequently, strategies that allow for efficient and rapid incorporation of non‐canonical modifications into peptides in parallel formats are highly sought after.
Marius Werner   +2 more
wiley   +1 more source

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

open access: yesChemistry – A European Journal, Volume 32, Issue 28, 25 July 2026.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve   +4 more
wiley   +1 more source

Tuning of electronic, optical and lipophilic behaviours of adamantane through various substitutions

open access: yesMaterials Research Express
Successive tuning of electronic, optical and lipophilic characteristics of adamantane molecules are obtained by various halogen substitutions at bridgehead and bridge positions of adamantane.
Aravindhan R   +2 more
doaj   +1 more source

Hydrosilane Chemistry: From Historic First Steps to Modern Applications

open access: yesEuropean Journal of Inorganic Chemistry, Volume 29, Issue 21, 25 July 2026.
This review covers the history of hydrosilanes, from their initial discovery to their modern applications. It highlights the pioneering work of chemists like Alfred Stock and Franz Fehér and discusses the modern ways of synthesis and use of hydrosilanes in printed electronics.
Uwe Böhme, Maik Gerwig
wiley   +1 more source

Synthesis of Benzopyran Atropisomers via Electrophilic Halogenation

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 27, 17 July 2026.
We report a halogenation‐based method for the synthesis of axially chiral benzopyrans, tolerating diverse substituents and halogens (Br, Cl, and I). A double bromination gives bisbenzopyrans with two stereogenic axes. Preliminary enantioselective conditions yield benzopyran atropisomer with up to 56% ee.
Alix Bourhis   +3 more
wiley   +1 more source

Study on the Synthesis of Fatty Alcohol-polyoxyethylene Ether Chloride Catalyzed by Ionic Liquid

open access: yes工程科学与技术, 2017
:The cationic surfactant of fatty alcohol-polyoxyethylene ether is a multi-functional surfactant, which played an important role in the industry of detergent, textile and so on.
zhenfangchen   +3 more
doaj  

How Fe(II)/2-Oxoglutarate Oxygenase Chooses Chlorination over Hydroxylation: Electric Field-Driven Ligand Exchange Governs C-Cl Formation. [PDF]

open access: yesJ Am Chem Soc
Jaber Sathik Rifayee SB   +6 more
europepmc   +1 more source

One-Pot Amidation/C─H Halogenation by an Efficient Electrochemical Cascade. [PDF]

open access: yesAngew Chem Int Ed Engl
Ponra S   +8 more
europepmc   +1 more source

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