Results 281 to 290 of about 66,822 (374)

Palladium‐Catalyzed Dual Csp2─Csp3 Bond Formation: A Versatile Platform for the Synthesis of Benzo‐Fused Heterocycles

open access: yesAdvanced Science, EarlyView.
Pd(II)/Cu(I) co‐catalyzed dual Csp2─Csp3 bonds construction from unactivated alkenes and arylsulfonyl chlorides to access benzo‐fused heterocycles with high efficiency and chemoselectivity. Abstract Transition‐metal‐catalyzed transformations offer a powerful approach to rapidly synthesize complex benzo‐fused heterocycles, crucial for drug and material ...
Jiahui Huang   +9 more
wiley   +1 more source

Multispectral Photonic Structural Colors via Enhanced Interfacial Interference of Ultrathin Cellulose Nanofiber/MXene Films

open access: yesAdvanced Science, EarlyView.
Fabrication of CNF‐MXene free‐standing films: Ti3C2Tx MXene flakes integrated into a cellulose nanofiber (CNF) matrix through layered self‐assembly using vacuum‐assisted filtration. The layered structure of 4 µm thickness is displayed on SEM image.
Valeriia Poliukhova   +7 more
wiley   +1 more source

In Silico Identification of 2,4-Diaminopyrimidine-Based Compounds as Potential CK1ε Inhibitors. [PDF]

open access: yesPharmaceuticals (Basel)
Sánchez-Álvarez AA   +2 more
europepmc   +1 more source

Radical‐Polar Crossover Bicyclization Enables a Modular Synthesis of Saturated Bicyclic Amines

open access: yesAdvanced Science, EarlyView.
Herein, we report the successful realization of a radical‐polar crossover bicyclization reaction from easily available cyclopropylamines and substituted alkenes through photoredox catalysis. This approach introduces an innovative methodology for the de novo synthesis of a diverse collection of 4/5‐, 5/5‐, 6/5‐,7/5‐ and 5/6‐fused saturated bicyclic ...
Dewei Feng   +4 more
wiley   +1 more source

Hydrocyclization/Defluorination of CF3‐Substituted Acrylamides: Insights from Kinetics of Hydrogen Atom Transfer

open access: yesAdvanced Science, EarlyView.
The study develops a H•/H– transfer strategy enabling efficient hydrocyclization/defluorination of CF3‐acrylamides to synthesize Seletracetam derivatives with gem‐difluoroalkenes. Mechanistic studies reveal distinct pathways: the NiII‐H/PhSiH3 system operates through a hydrogen atom transfer process, while the 1,4‐Michael addition of H– appears to be ...
Yanjun Wan, Ronghui Shao, Jack R. Norton
wiley   +1 more source

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