Results 191 to 200 of about 839,047 (377)

Magnetic clock for a harmonic oscillator

open access: yesPhysical Review A
We present an implementation of a recently proposed procedure for defining time, based on the description of the evolving system and its clock as non-interacting, entangled systems, according to the Page and Wootters approach. We study how the quantum dynamics transforms into a classical-like behaviour when conditions related with macroscopicity are ...
Coppo, A, Cuccoli, A, Verrucchi, P
openaire   +2 more sources

Quantum Chemistry Based Simulation of Enantioseparation on Cyclodextrin‐ and Polysaccharide‐Based Chiral Stationary Phases

open access: yesChemistry – A European Journal, EarlyView.
We employed a systematic quantum chemistry‐based computational approach for simulating chiral HPLC, incorporating high‐level DFT methods. For the popular polysaccharide‐based CSPs, 90%$\%$ of determined elution orders were computed correctly. Abstract We assess the capability of modern quantum chemical methods to simulate enantioseparation on chiral ...
Linda Nelles‐Ziegler   +2 more
wiley   +1 more source

N‐Heterocyclic Carbene Stabilized Bisacylgermylenes

open access: yesChemistry – A European Journal, EarlyView.
We developed a metal‐free strategy for acyl group abstraction, enabling access to novel germenolates 2a,b, or NHC‐stabilized bisacylgermylenes 4a,b. This novel class of germylenes exhibit nucleophilic reactivity toward iron and boron electrophiles, and can alternatively be prepared by the reaction of dichlorobisacylgermane and geminal bisgermenolate at
Matthias Paris   +3 more
wiley   +1 more source

Linear and Two‐Dimensional Infrared Spectroscopy of the Multifunctional Vibrational Probe, 3‐(4‐Azidophenyl) Propiolonitrile. Deperturbing a Fermi Triad by Isotopic Substitution

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Linear infrared spectroscopy combined with isotope labeling and density functional theory unravels the origin of a Fermi triad in a multifunctional vibrational chromophore. Ultrafast 2DIR‐spectroscopy reports directly on the dynamics and the intramolecular vibrational energy flow pathways in the isotopically deperturbed system. Abstract Infrared probes
Claudia Gräve   +4 more
wiley   +1 more source

High-Power and High-Efficiency Millimeter-Wave Harmonic Oscillator Design, Exploiting Harmonic Positive Feedback in CMOS

open access: yesIEEE transactions on microwave theory and techniques, 2017
Rouzbeh Kananizadeh, O. Momeni
semanticscholar   +1 more source

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