Stepwise Acetylene Insertion and Ammonia Activation at a Digallene and Diindene
The stepwise insertion of acetylene into the E═E bonds of digallenes and diindenes is reported. This leads to the selective formation of four‐ and six‐membered rings with 2π E2C2 and 4π E2C4 cores. The six‐membered cyclohexadiene analogues are Lewis‐acidic and can form stable, isolable adducts with ammonia, which—upon heating—undergo ammonolysis ...
Álvaro García‐Romero+2 more
wiley +2 more sources
Dexmedetomidine-enhanced chest wall fascial plane blocks in ultra-fast-track minimally invasive heart valve surgery: a randomized controlled trial. [PDF]
Jiang SJ+5 more
europepmc +1 more source
This study investigated changes in pulmonary artery hemodynamics using a Flowire catheter and evaluated the accuracy of Doppler echocardiography in dogs with acute pulmonary thromboembolism (PTE). Ten healthy beagles were anesthetized, and acute pulmonary hypertension (PH) was induced by injecting 300‐μm dextran microspheres.
Tomohiko Yoshida+3 more
wiley +1 more source
Automated Iterative N─C and C─C Bond Formation
Automated iterative assembly of MIDA or TIDA boronate building blocks enables generalized and automated preparation of many different types of small functional molecules in a modular fashion. However, until now, this engine could not leverage nitrogen atoms as iteration handles, excluding molecules rich in N─C and C─C bonds.
Theodore Tyrikos‐Ergas+14 more
wiley +2 more sources
A Dedicated Transcatheter Heart Valve for Native Aortic Regurgitation in Patients With Significant Aortic Angulation. [PDF]
Mendez Hirata G+10 more
europepmc +1 more source
Nanostructured Biomaterial‐Based Approaches to Support Induced Pluripotent Stem Cell Differentiation
Induced pluripotent stem cells (iPSCs), reprogrammed from adult somatic cells, represent an innovative approach for regenerative medicine and biomedical applications. This review highlights the importance of nanostructured biomaterials, utilized as delivery systems or scaffolds, in supporting iPSC differentiation and fate through structural and ...
Beatriz A. B. R. Passos+2 more
wiley +1 more source
Usefulness of Myocardial Injury Parameters in Predicting Prolonged Postoperative Use of Inotropes Drugs in Patients Undergoing Heart Valve Surgery. [PDF]
Duchnowski P, Śmigielski W, Kołsut P.
europepmc +1 more source
Progression of Paravalvular Leak and Hemolytic Anemia After Implantation of Fifth-Generation Balloon-Expandable Transcatheter Heart Valve. [PDF]
Kanehama N+5 more
europepmc +1 more source
Exercise-Based Cardiac Rehabilitation for Patients After Heart Valve Surgery: A Systematic Review and Re-Evaluation With Evidence Mapping Study. [PDF]
Zhang R, Zhu C, Chen S, Tian F, Chen Y.
europepmc +1 more source