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Tailored Polymer‐Based SEI via iCVD for Stable Zinc Metal Anodes in Aqueous Batteries through Modulation of Hydrophilicity and Elasticity to Inhibit Hydrogen Evolution Reactions

open access: yesAdvanced Functional Materials, EarlyView.
A stretchable and superhydrophobic pF1V1 polymer layer is conformally coated on Zn metal via iCVD, forming a water‐repelling interphase that inhibits the hydrogen evolution reaction. This tailored interface maintains excellent electrolyte compatibility while suppressing dendrite growth, thereby enhancing the long‐term electrochemical stability of Zn ...
Jaeyeon Lee   +12 more
wiley   +1 more source

Flexibility and Dynamicity Enhances and Controls Supramolecular Self‐Assembly of Zinc(II) Metallogels

open access: yesAdvanced Functional Materials, EarlyView.
Zinc(II) coordination complexes with tunable aryloxy‐imine ligands exhibit controllable supramolecular self‐assembly into hierarchical fibrous structures. Coordination‐driven stacking, not π–π interactions, enables gelation, dynamic assembly/disassembly, and enhanced nanomechanical properties.
Merlin R. Stühler   +10 more
wiley   +1 more source

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