Results 41 to 50 of about 128,089 (280)

Microwave-Assisted Synthesis and Evaluation of Antimicrobial Activity of 3-{3-(s-Aryl and s-Heteroaromatic)acryloyl}-2Hchromen-2-one Derivatives [PDF]

open access: yes, 2010
The exploration of potential utilization of microwaves as an energy source for heterocyclic synthesis was herein investigated using condensation of 3-acetylcoumarin (1) with aromatic and heteroaromatic aldehydes to afford the corresponding aromatic ...
Ajani   +47 more
core   +1 more source

3-Amino-4-(diphenylamino)-1H-2-benzopyran-1-one

open access: yesMolbank, 2022
Various synthetic methodologies to obtain 3,4-diaminoisocumarin nucleus have been reported and described. However, mechanistic analysis based on experimental evidence is lacking. Herein, we report the synthesis of the novel 3-amino-4-(diphenylamino)-1H-2-
Felipe Quiroga-Suavita   +2 more
doaj   +1 more source

Triazole-Directed Pd-Catalyzed C(sp2)–H Oxygenation of Arenes and Alkenes [PDF]

open access: yes, 2016
Selective Pd-catalyzed C(sp2)–H oxygenation of 4-substituted 1,2,3-triazoles is described. Unlike previous metal-catalyzed C–H functionalization events, which preferentially occur at the activated heterocyclic C–H bond, the regioselective oxygenation of ...
Aizpurua Iparraguirre, Jesús María   +2 more
core   +2 more sources

Asymmetric Synthesis of 1-Heteroaryl-1-arylalkyl Tertiary Alcohols and 1-Pyridyl-1-arylethanes by Lithiation-Borylation Methodology [PDF]

open access: yes, 2013
The synthesis of highly enantioenriched alpha-heterocyclic tertiary alcohols has been achieved via lithiation-borylation of a configurationally stable lithiated carbamate and heterocyclic pinacol boronic esters followed by oxidation. Protodeboronation of
Aggarwal V. K.   +41 more
core   +3 more sources

Highly Efficient and Diastereoselective Synthesis of New Pyrazolylpyrrolizine and Pyrazolylpyrrolidine Derivates by a Three-Component Domino Process

open access: yesMolecules, 2014
Diastereoselective reactions between 4-formylpyrazoles, N-substituted maleimides and glycine derivates led to new series of pyrazolyldipyrrolo [3,4-a:3',4'-f]pyrrolizines and pyrazolylpyrrolo[3,4-c]pyrroles in good yields.
Jairo Quiroga   +6 more
doaj   +1 more source

Bulky-yet-flexible carbene ligands and their use in palladium cross-coupling [PDF]

open access: yes, 2019
In recent years, several classes of new N-heterocyclic carbene (NHC) ligands were developed around the concept of flexible steric bulk. The steric hindrance of these ligands brings stability to the active species, while ligand flexibility still allows ...
Cazin, Catherine   +2 more
core   +1 more source

Traceless Redox-Annulations of Alicyclic Amines

open access: yesSynOpen, 2020
Amines such as 1,2,3,4-tetrahydroisoquinoline undergo redox­-neutral annulations with ortho-(nitromethyl)benzaldehyde. Benzoic­ acid acts as a promoter in these reactions, which involve concurrent amine α-C–H bond and N–H bond functionalization ...
Dillon R. L. Rickertsen   +4 more
doaj   +1 more source

Synthesis of nanocellulose aerogels and Cu-BTC/nanocellulose aerogel composites for adsorption of organic dyes and heavy metal ions

open access: yesScientific Reports, 2021
MOFs compounds with open metal sites, particularly Cu-BTC, have great potential for adsorption and catalysis applications. However, the powdery morphology limits their applications. One of the almost new ways to overcome this problem is to trap them in a
Nuhaa Shaheed   +4 more
doaj   +1 more source

Preparation of α-chitin-based nanocomposite as an effective biocatalyst for microwave aided domino reaction

open access: yesHeliyon, 2019
In this paper, chitin (Ch) was extracted by an optimized method from cuttlebone of the Persian Gulf cuttlefish (Sepiidae, Cephalopoda). The extracted chitin was characterized by Fourier-transform infrared spectroscopy (FT-IR), X-ray powder diffraction ...
Sarvenaz Abolghassem   +2 more
doaj   +1 more source

Latent olefin metathesis catalysts [PDF]

open access: yes, 2009
Olefin metathesis is a versatile synthetic tool for the redistribution of alkylidene fragments at carbon-carbon double bonds. This field, and more specifically the development of task-specific, latent catalysts, attracts emerging industrial and academic ...
Drozdzak, Renata   +4 more
core   +2 more sources

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