Experimental and computational studies elucidate how the electronic nature of substituents controls the ring‐opening temperature and diradical character of 1‐substituted benzocyclobutenes, enabling the rational design of o‐quinodimethane‐based synthetic transformations.
Magali Dallegre +8 more
wiley +1 more source
A phosphinine–borane Lewis pair shows a dynamic mode of water addition, revealing reversible and regioselective transformations that expand the reactivity of aromatic phosphorus heterocycles and open pathways to stimuli‐responsive systems for catalysis, small‐molecule activation, and functional materials.
Samantha Frank +7 more
wiley +1 more source
In silico and in vitro prediction of new synthesized N-heterocyclic compounds as anti-SARS-CoV-2. [PDF]
Hashem HE, Ahmad S, Kumer A, Bakri YE.
europepmc +1 more source
High‐Energy‐Density Redox Flow Batteries: Mechanisms, Design Strategies, and Recent Progress
ABSTRACT The inherent intermittency of energy sources such as solar and wind power hinders the transition to renewable energy, necessitating advanced energy storage solutions. Enhancing energy density is crucial for lowering system costs and enabling large‐scale deployment.
Xiaolian Zhao +8 more
wiley +1 more source
Heterocyclic compounds as xanthine oxidase inhibitors for the management of hyperuricemia: synthetic strategies, structure-activity relationship and molecular docking studies (2018-2024). [PDF]
Singh A, Debnath R, Chawla V, Chawla PA.
europepmc +1 more source
Composite materials based on metal nanoparticles supported on a naturally occurring nanotubular clay, halloysite (HAL), led to the diastereoselective hydrogenation of tetra‐substituted alkenes under relatively smooth conditions, mainly oxazolidinone‐based heterocycles.
Rosa Pich +9 more
wiley +1 more source
Alkyl Bismuth Cations: Synthesis, Characterization, and Application as Z‐Type Ligands
Rare examples of alkyl bismuth cations [BiR2(SbF6)] are presented, including cyclopropyl ligands and a bismacyclic structure. The bismuth‐centered Lewis acids act as Z‐type ligands toward the electron‐rich platinum atom in [Pt(PCy3)2], generating a set of metal‐only Lewis pairs. The structural and spectroscopic properties of these rare types of bismuth
Johannes Schwarzmann +7 more
wiley +1 more source
One-pot synthesis of quinazolinone heterocyclic compounds using functionalized SBA-15 with natural material ellagic acid as a novel nanocatalyst. [PDF]
Mohassel Yazdi N, Naimi-Jamal MR.
europepmc +1 more source
Insights into the Photocatalytic Arene Bromination Enabled by Cs2AgBiBr6 Microparticles
A sustainable photocatalytic bromination of electron‐rich arenes is enabled by low‐toxicity Cs2AgBiBr6 double‐perovskite microparticles using HBr as an atom‐economical bromine source. Surface‐derived bromine radicals drive highly selective mono‐bromination under mild conditions.
Daniele Conelli +8 more
wiley +1 more source
Bifunctional Photocatalysts: Exploiting Proximity for Enhanced Reaction Performance
This review covers the application of the bifunctional approach to photocatalysis as a means to attain (enhanced) enantioselectivity, and, more in general, as a strategy to enhance the catalytic performance through an effective use of short‐lived reaction intermediates.
Luigi Dolcini +3 more
wiley +1 more source

