Expedient Discovery of a Metallaphotoredox Cyanomethylation for Synthesizing α‐Aryl Nitriles
A metallaphotoredox cyanomethylation reaction has been developed for the synthesis of valuable α‐aryl nitrile intermediates. The methodology was successfully applied to diverse medicinally‐relevant substrates, providing an expedient route to anti‐cancer Senexin compounds, while also removing the need for toxic cyanide reagents. The mechanism was probed
Gemma C. Cook +6 more
wiley +1 more source
Integration of heterogeneous photocatalysis and persulfate based oxidation using TiO2-reduced graphene oxide for water decontamination and disinfection. [PDF]
John D, Jose J, Bhat SG, Achari VS.
europepmc +1 more source
π-Conjugated polyHIPEs as highly efficient and reusable heterogeneous photosensitizers [PDF]
Antonietti, Markus +4 more
core +1 more source
Nanowire Photoelectrochemistry. [PDF]
Recent applications of photoelectrochemistry at the semiconductor/liquid interface provide a renewable route of mimicking natural photosynthesis and yielding chemicals from sunlight, water, and air.
Deng, Jiao +5 more
core
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis +2 more
wiley +1 more source
Impact of Reaction Parameters and Water Matrices on the Removal of Organic Pollutants by TiO2/LED and ZnO/LED Heterogeneous Photocatalysis Using 365 and 398 nm Radiation. [PDF]
Náfrádi M +3 more
europepmc +1 more source
Machine‐learning potentials are increasingly taking on the exploratory tasks of homogeneous catalysis, enabling rapid conformer sampling and reaction‐space mapping. However, when selectivity depends on subtle electronic effects, electronic‐structure methods remain essential.
Maxime Ferrer +3 more
wiley +1 more source
Treatment of electrochemical plating wastewater by heterogeneous photocatalysis: the simultaneous removal of 6:2 fluorotelomer sulfonate and hexavalent chromium. [PDF]
Kim HH, Gilak Hakimabadi S, Pham AL.
europepmc +1 more source
S‐Doped Carbon Nitride Thin Films From a Triazole Precursor
Sulfur‐functionalized carbon nitride thin films are synthesized via low‐temperature chemical vapor deposition using a triazole‐derived precursor. Tunable sulfur incorporation modulates electronic and optical properties and enables efficient visible‐light photocatalysis with high conversion and selectivity.
Yen‐Han Wang +3 more
wiley +1 more source
A Comparison of RML Prion Inactivation Efficiency by Heterogeneous and Homogeneous Photocatalysis
Prions are proteinaceous pathogens responsible for a variety of devastating diseases in mammals, including scrapie in sheep and goats, chronic wasting disease in cervids, and Creutzfeldt–Jakob disease (CJD) in humans.
Ioannis Paspaltsis +8 more
doaj +1 more source

