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Hydrogen bonded network of protonated hexacyanoferrate anions is determined by geometry and halogen bonding proclivity of the halogenopyridinium cation.
Nikola Jakupec +2 more
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Synthesis and Properties of Hexacyanoferrate Interlayered in Hydrotalcite. I. Hexacyanoferrate(II)
Clays and Clay Minerals, 1994AbstractHydrotalcite (HT) interlayered with hexacyanoferrate(II) ions ([Mg4.62Al1.52(OH)12][(Fe(CN)6)0.30-(CO3)0.29]) has been synthesized from the carbonate-HT ([Mg4.52Al1.50(OH)12][(CO3)0.77]) through double ion exchange reactions, and the products have been studied by chemical and physical methods.
Christian B. Koch +1 more
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Hexacyanoferrate-Interlayered Hydrotalcite
Solid State Ionics, 1996Abstract Hexacyanoferrate(II) and hexacyanoferrate(III) hydrotalcites have been synthesized by exchange of originally existing carbonate ions at pH = 4.5. The samples have been characterized by elemental chemical analysis, powder X-ray diffraction, FT-IR and X-ray absorption spectroscopies, nitrogen adsorption for specific surface area and porosity
Vicente Rives, P Malet, M J Holgado
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The reaction of lucigenin (Lc) with potassium hexacyanoferrate is accompanied by the appearance of charge-transfer bands in the visible spectral region and yields Lc{H}2[Fe(CN)6] · 4H2O in an acidic medium and Lc4[Fe(CN)6](NO3)5 · 18H2O in a neutral medium in air.
V. Yu. Kotov +2 more
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Solvent effects on the redox potential of hexacyanoferrate(III)-Hexacyanoferrate(II)
Inorganica Chimica Acta, 1976Abstract The redox behaviour of the system hexacyanoferrate(III)-hexacyanoferrate(II) has been studied by polarographic and voltammetric methods in the following solvents: N-methylpyrrolidinone, N,N-dimethylformamide, acetonitrile, dimethylsulfoxide, N,N-dime-thylthioformamide,1,2-propanediolcarbonate, nitromethane, ethanol, methanol and water.
V. Gutmann +2 more
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Development of biosensors based on hexacyanoferrates
Talanta, 2000Ferric and copper hexacyanoferrates (PB and CuHCF, respectively) were electrodeposited on glassy carbon electrodes providing a suitable catalytic surface for the amperometric detection of hydrogen peroxide. Additionally glucose oxidase was immobilized on top of these electrodes to form glucose biosensors.
de Mattos, I. L. +4 more
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Inhibition of transketolase by hexacyanoferrate(III)
Biochemistry (Moscow), 2010The effect of hexacyanoferrate(III) on the catalytic activity of transketolase has been studied. This oxidant inactivates only one of two active sites of the enzyme, the one with a higher affinity to the coenzyme (thiamine diphosphate). The second active site does not lose its catalytic activity.
V A, Yurshev +3 more
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