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Disordered multicomponent systems, occupying the mostly uncharted centres of phase diagrams, were proposed in 2004 as innovative materials with promising applications. The idea was to maximize the configurational entropy to stabilize (near) equimolar mixtures and achieve more robust systems, which became known as high-entropy materials.
Corey Oses +2 more
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Flexible high-entropy functional ceramics. [PDF]
Functional ceramics, once integrated with flexibility, hold great promise for cutting-edge electronic devices. Unfortunately, functionality and flexibility are inherently exclusive in ceramics: the long-range order of ionic lattices bestows polarization-like properties that accompany brittleness, whereas disorder tolerates bond rotation to generate ...
Dou L +22 more
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How high is the entropy in high entropy ceramics? [PDF]
In this Perspective, I raise the question whether the terms high entropy ceramics, high entropy nitrides, high entropy oxides, high entropy borides, etc., are meaningful considering the magnitude of the calculated configurational entropy. Here, the origin of Boltzmann's equation is reviewed and the implications for application are discussed.
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High-entropy ceramics: Propelling applications through disorder
Disorder enhances desired properties, as well as creating new avenues for synthesizing materials. For instance, hardness and yield stress are improved by solid-solution strengthening, a result of distortions and atomic size mismatches. Thermo-chemical stability is increased by the preference of chemically disordered mixtures for high-symmetry super ...
Cormac Toher +8 more
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Binary and ternary transition metal carbides are stable ceramic crystals with outstanding mechanical properties. In recent years, multicomponent single-phase high entropy alloys enjoyed explosive growth due to many of their outstanding physical ...
Saro San, Wai-Yim Ching
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Entropy engineering has attracted extensive attention, which is applied to induce controllable changes in structures through lattice distortion effects to optimize certain properties. In this work, a series of pure phase high-entropy dielectric ceramics,
Zhihao Lou +7 more
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Temperature-dependent thermal expansivities of silicate melts: The system anorthite-diopside [PDF]
The temperature-dependent thermal expansivities of melts along the join anorthite-diopside have been determined on glassy and liquid samples using a combination of calorimetry, dilatometry, and Pt double bob Archimedean densitometry.
Dingwell, Donald B. +2 more
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Physical structure of P(VDF-TrFE)/barium titanate submicron composites [PDF]
Dynamic Dielectric Spectroscopy and Thermo Stimulated Current were used to investigate of the dielectric relaxation of hybrid Poly(vinylidene-fluoride-trifluoroethylene)/barium titanate 700 nm composites with 0–3 connectivity.
Capsal, Jean-Fabien +3 more
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Extremely hard and tough high entropy nitride ceramics [PDF]
AbstractSimultaneously hard and tough nitride ceramics open new venues for a variety of advanced applications. To produce such materials, attention is focused on the development of high-entropy ceramics, containing four or more metallic components distributed homogeneously in the metallic sublattice.
Moskovskikh, Dmitry +8 more
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High-entropy perovskite ceramics: Advances in structure and properties [PDF]
High-entropy ceramic materials usually refer to the multi-principal solid solution formed by 5 or more ceramic components. Due to its novel “high-entropy effect” and excellent performance, it has become one of the research hotspots in the field of ...
Ding Yiwen +10 more
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