Results 241 to 250 of about 211,770 (338)

Room‐Temperature Helix‐to‐Disc Conversion of Thia[6]helicene S,S‐Dioxides to Coronene via In Situ Phenoxide Anion Generation

Chemistry – A European Journal, EarlyView.
In situ phenoxide formation at the benzene terminus triggers room‐temperature conversion of thia[6]helicene S,S‐dioxides to coronene. The solubility contrast drives product precipitation, enabling isolation by simple filtration. This pericyclic annulation between the helical termini provides direct access to coronene‐type planar architectures ...
Kaito Seino, Takashi Murase
wiley   +1 more source

Amine‐Triggered Azabenz‐Annulation of Cyclic Secondary Amine‐Functionalized Perylene Diimides for Dual‐Mode Sensing

Chemistry – A European Journal, EarlyView.
Pictet‐Spengler Intermediate of a cyclic secondary amine perylene diimide undergoing amine‐triggered conversion to azabenz‐annulated perylene diimide, inducing a high‐contrast green‐to‐yellow color change along with fluorescence turn‐on, demonstrating intuitive “safe” to “warning” dual‐mode sensing.
Irene E. Park, Alejandro J. Cuellar de Lucio, Gregory C. Welch   +2 more
wiley   +1 more source

Three‐Step Synthesis Toward Fluorene‐Based Non‐Fused‐Ring Acceptors for Organic Solar Cells

Chemistry – A European Journal, EarlyView.
Applying a simple three step synthesis strategy leads to two fluorene‐based non‐fused‐ring electron acceptors, FHM‐Cl and FHM‐F for organic solar cells. The chlorinated variant delivers markedly higher efficiency due to broader light harvesting and favorable molecular packing, resulting in improved charge transport and reduced recombination losses ...
Virginia Lafranconi, Suman Mallick, Lisa Nauta, Lisa Inzko, Julia Hönigsberger, Danijel Babic, Bettina Schlemmer, Daniele Padula, Heinz Amenitsch, Thomas Rath, Gregor Trimmel   +10 more
wiley   +1 more source

When Light Challenges Heat: Mechanistic Insights Into a Reaction Competing With Cadogan Cyclisation in Nitro‐Perylenediimides

Chemistry – A European Journal, EarlyView.
Visible‐light irradiation of nitro‐perylenediimide in the presence of triphenylphosphine reveals an unexpected pathway competing with the classical Cadogan cyclization. Mechanistic investigations uncover the rapid and selective formation of bay‐functionalized 1‐iminophosphorane‐12‐hydroxy perylenediimide derivatives.
Manuel Pedrón Laserna, Ilaria Ciofini, Piétrick Hudhomme   +2 more
wiley   +1 more source

Pyropheophytin a accompanies pheophytin a in darkened light grown cells of Euglena [PDF]

, 1981
Rüdiger, W., Scheer, Hugo, Schiff, J. A., Schoch, S., Siegelmann, H. W.   +4 more
core  

Synthesis and characterization of amphiphilic nitroxide 1,1,3,3–tetraethylisoindoline–2–oxyl–5–sodium sulfonate (TEIOSNa)

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract The synthesis and characterization of an amphiphilic nitroxide to be used as a controlling agent in a nitroxide‐mediated living radical polymerization in aqueous dispersion media is presented. In the first stage of nitroxide synthesis (phthalimide protection), two reaction methods were employed: traditional and microwave.
Enrique García‐Leal, Martha Eugenia Albores Velasco, René O. Vargas, Rubén Mil‐Martínez   +3 more
wiley   +1 more source

Hydroprocessing of synthetic kerosene over a non‐sulphided Ni/Al2O3 catalyst: Impact of alcohols and ketones on alkene conversion

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract Synthetic jet fuel containing non‐petroleum‐derived kerosene can be produced from synthetic kerosene obtained through processes that include a hydroprocessing step. The potential use of non‐sulphided (reduced) nickel supported on alumina (Ni/Al2O3) was evaluated as an alternative to sulphided catalysts to saturate alkenes in sulphur‐free ...
Garima Chauhan, Felix Link, Cibele Melo Halmenschlager, Arno de Klerk   +3 more
wiley   +1 more source

Multifunctional Heterocyclic Scaffolds for Hybrid Lewis Acid/Lewis Base Catalysis of Carbon–Carbon Bond Formation [PDF]

, 2016
Benoit, Adam R., Dockendorff, Chris, Huff, Raechel, Lindeman, Sergey, Meyle, Elisia, Porter, Jacob D., Wiedenhoeft, Dennis, Wu, Yibiao, Yeung, Teresa H.W.   +8 more
core   +1 more source

Protocol for Reconstituting Adaptor‐Mediated Activation of Full‐Length Kinesin‐1

Cytoskeleton, EarlyView.
ABSTRACT Kinesin‐1 is a member of the kinesin superfamily that plays an essential role in intracellular cargo transport. In the absence of cargo, Kinesin‐1 exhibits low motor activity due to autoinhibition. Multiple studies have demonstrated that adaptor proteins, which link cargos to Kinesin‐1, can activate Kinesin‐1 by releasing the autoinhibition ...
Haruka Masumoto, Kyoko Chiba
wiley   +1 more source

Synergistic Engineering of Oxygen Vacancies and Topological Surface States in Bi2Te3/TiO2‐X Heterostructures for Highly Efficient Photothermal‐Driven CO2 Photoreduction

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Integrating the topological insulator Bi2Te3 with oxygen‐deficient TiO2‐X creates a synergistic platform for full‐spectrum CO2 reduction, achieving high‐selectivity C2+ production via enhanced photothermal catalysis and tailored charge dynamics.
Bingke Zhang, Chenchen Zhao, Jing Qiao, Changcun Li, Yang Wang, Xingshuo Liu, Dongbo Wang, Gang Liu, Zhao Qian, Rajeev Ahuja, Jinzhong Wang, Degang Zhao   +11 more
wiley   +1 more source