Bay‐functionalized [7]Helicene Bilayer Nanographenes
Advanced Optical Materials, EarlyView.Bay‐functionalized [7]helical bilayer nanographenes are synthesized via a scalable, modular strategy enabling late‐stage diversification. Tailored methoxy, diketone, and phenazine substitutions precisely tune redox, photophysical, and chiroptical properties, delivering strong electronic circular dichroism and bright circularly polarized luminescence ...
Anmol Thanai +9 more
wiley +1 more source
Kinetically stabilized 1,3-diarylisobenzofurans and the possibility of preparing large, persistent isoacenofurans with unusually small HOMO-LUMO gaps. [PDF]
Beilstein J Org ChemLiu Q, Miller GP.
europepmc +1 more source
Trans Influence and Substituent Effects on the HOMO-LUMO Energy Gap and Stokes Shift in Ru Mono-Diimine Derivatives. [PDF]
J Mol Struct, 2019 AlAbbad S +6 more
europepmc +1 more source
Substituent Effects on Cyanine Dyes Vary with Position and Chain Length
Advanced Optical Materials, EarlyView.In cyanines, substituent effects vary as a function of substituent position and cyanine length. Electron‐donating‐ and ‐withdrawing groups at meso‐ and α‐positions of 4n+1/4n−1 long cyanines (n = 1, 2, 3…) cause opposing, hypsochromic and bathochromic shifts of the 1st UV–vis absorption bands.
David Dunlop +2 more
wiley +1 more source
Correlation between Molecular Docking and the Stabilizing Interaction of HOMO-LUMO: Spirostans in CHK1 and CHK2, an In Silico Cancer Approach. [PDF]
Int J Mol SciRosales-López A +4 more
europepmc +1 more source
Do's and Don'ts When Visiting Circularly Polarized Luminescence
Advanced Optical Materials, EarlyView.This perspective presents our insights into the principles, challenges, and opportunities of circularly polarized luminescence (CPL). Highlighting key concepts such as the dissymmetry factor (glum) and molecular design strategies, we discuss advances in CPL efficiency, emerging NIR emitters, solid‐state applications, and the growing role of theory and ...
Rafael G. Uceda +9 more
wiley +1 more source
Exploring the Impact of the HOMO-LUMO Gap on Molecular Thermoelectric Properties: A Comparative Study of Conjugated Aromatic, Quinoidal, and Donor-Acceptor Core Systems. [PDF]
ACS OmegaBlankevoort N +11 more
europepmc +1 more source
Rational design of near-infrared absorbing organic dyes: Controlling the HOMO-LUMO gap using quantitative molecular orbital theory. [PDF]
J Comput Chem, 2018 Narsaria AK +5 more
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Advanced Optical Materials, EarlyView.Blue organic light‐emitting diodes (OLEDs) comprising triplet‐harvesting emitters require the use of high‐triplet‐energy hosts and blocking layers to confine the triplet excitons to the emitter. Here, we present efficient single‐layer blue hyperfluorescent OLEDs comprising solely of a matrix‐free emissive layer between two charge‐injecting electrodes ...
Xiao Tan +5 more
wiley +1 more source
Design of Molecular Lanthanide‐Based Quantum Light Sources for On‐Chip Integration
Advanced Optical Materials, EarlyView.Rigid lanthanide complexes with a tetrapodal tris‐benzimidazolic ligand exhibit narrow, well‐resolved visible/NIR emission profiles suitable for quantum photonics. The EuL complex features an exceptionally sharp 5D₀→7F₀ transition enabled by an LMCT mechanism that suppresses inhomogeneous broadening.
Silvia Bonabello +10 more
wiley +1 more source