Results 91 to 100 of about 717,910 (299)

Recent Advances in the Synthesis of 2-Imidazolines and Their Applications in Homogeneous Catalysis

, 2009
As an important class of heterocyclic scaffolds. 2-imidazolines have attracted the attention from the chemists interested in natural products, pharmaceutical chemistry, synthetic organic chemistry. coordination chemistry, and homogeneous catalysis.
Da‐Ming Du, Liu, Han, Du, Da-Ming, Han Liu, Du, Da Ming   +4 more
core   +1 more source

Homogeneous and Heterogeneous Catalysis Impact on Pyrolyzed Cellulose to Produce Bio-Oil

, 2020
Effectively utilizing catalytic pyrolysis to upgrade bio-oil products prepared from biomass has many potential benefits for the environment. In this paper, cellulose (a major component of plants and a biomass model compound) is pyrolyzed and catalyzed ...
Jeffrey S. Cross, Siyi Li, Shuo Cheng
core   +1 more source

Photo‐Degradable Polyester Networks and Multi‐Photon Printed Objects Based on Cyclic Ketene Acetals

Advanced Functional Materials, EarlyView.
The current work introduces a photoreversible polyester network derived from radical ring‐opening polymerization of cyclic ketene acetals. It combines photoreversible cross‐linking with initiator‐free multi‐photon printing. Reversible network formation, tunable mechanical properties, and selective degradation highlight its potential as a versatile ...
Till Meissner, Julian Fanelli, Vinh Xuan Truong, Rob Jones, Jens Gaitzsch, Christopher Barner‐Kowollik   +5 more
wiley   +1 more source

Electron‐Deficient Linkers Enhance H2O2 Electrosynthesis in Covalent Organic Frameworks

Advanced Functional Materials, EarlyView.
Linker π‐conjugation modulates the electronic state of the Ni–N4 centers and their interaction with the key *OOH intermediate while preserving the primary coordination motif. NiPc‐PTDA delivers an H2O2 selectivity of 92% and a production rate of 34.8 mol gcat−1 h−1, highlighting linker electronic properties as a molecular design parameter for NiPc ...
Houting Xie, Rui Guo, Zhen Liu, Yang Hu, Laichun Zhao, Omid Mazaheri, Bufeng Zhang, Shuaijun Pan   +7 more
wiley   +1 more source

Synthesis, Immobilization and Catalytic Activity of a Copper(II) Complex with a Chiral Bis(oxazoline)

Molecules, 2014
A chiral bis(oxazoline) bearing CH2OH groups was synthesized from a commercial bis(oxazoline) and characterized by 1H- and 13C-NMR, high resolution ESI-mass spectrometry and FTIR. The corresponding copper(II) complex was immobilized onto the surface of a
Liliana Carneiro, Ana R. Silva, Peter S. Shuttleworth, Vitaly Budarin, James H. Clark   +4 more
doaj   +1 more source

Decomposition pathways of homogeneous catalysts

, 2001
Homogeneous catalysts can decompose in a variety of ways: metal deposition, ligand decomposition, reaction with impurities, dimer formation, and reaction of the metal center with the ligand.
van Leeuwen, P.W.N.M., Piet W.N.M. van Leeuwen   +1 more
core   +1 more source

Architecture‐Driven Functional Coupling in Vertically Aligned Nanocomposites

Advanced Functional Materials, EarlyView.
Vertically aligned nanocomposites define a growth‐engineered architecture in which vertical interfaces, strain fields, defect pathways, and phase connectivity are created simultaneously. This review shows how these architectural features couple ferroic, optical, ionic, electrochemical, and device responses, establishing design rules and open challenges
Md Shatil Islam‐Shanto, Javier Zamudio‐García, Abraham Sánchez‐Caballero, David Marrero‐López, Vincenzo Esposito   +4 more
wiley   +1 more source

Chemocatalytic Conversion of Cellulose into Key Platform Chemicals

International Journal of Polymer Science, 2018
Chemocatalytic transformation of lignocellulosic biomass to value-added chemicals has attracted global interest in order to build up sustainable societies.
Guangbi Li, Wei Liu, Chenliang Ye, Xiaoyun Li, Chuan-Ling Si   +4 more
doaj   +1 more source

Catalytic Organic Transformations Mediated by Actinide Complexes

Inorganics, 2015
This review article presents the development of organoactinides and actinide coordination complexes as catalysts for homogeneous organic transformations.
Isabell S. R. Karmel, Rami J. Batrice, Moris S. Eisen   +2 more
doaj   +1 more source

THE ELUCIDATION OF MECHANISMS IN HOMOGENEOUS CATALYSIS [PDF]

Comments on Inorganic Chemistry, 2009
After a reminder of the definition of common terms used in catalysis and reaction mechanisms, different chapters highlight the various approaches used for the elucidation of catalytic mechanisms, each with its own advantages and limitations. Kinetics investigations define the rate law and provide information on certain features of the reaction pathway ...
openaire   +2 more sources