Results 131 to 140 of about 717,910 (299)

Hydrophobic MFI‐Type Zeolites via Alkali‐Cation‐Induced Defect Healing: Implications for Adsorbent and Catalyst Design

Advanced Materials, EarlyView.
Sub‐stoichiometric amounts of Na+ or K+ enhance defect healing during Silicalite‐1 (MFI) and TS‐1 calcination by promoting Si–O–Si annealing and healing framework vacancies. The resulting defect‐free zeolites are more hydrophobic and show improved butanol/water separation and improved activity and selectivity in the epoxidation of 1‐hexene, offering a ...
Christos Kanteler, Pau Ferri, Francisco Javier Escobar‐Bedia, Álvaro Mayoral, Alejandro Vidal‐Moya, Richard Kendra, Chen Lei, Miguel Palomino, Fernando Rey, Lukáš Grajciar, Christopher James Heard, Pedro Serna, Mercedes Boronat, Cristina Martínez, Manuel Moliner   +14 more
wiley   +1 more source

Homogeneous Catalysis and Heterogeneous Recycling: A Simple Zn(II) Catalyst for Green Fatty Acid Esterification. [PDF]

ACS Sustain Chem Eng, 2021
Melchiorre M, Cucciolito ME, Di Serio M, Ruffo F, Tarallo O, Trifuoggi M, Esposito R.   +6 more
europepmc   +1 more source

Gold‐Stabilized Copper Enables Anodic Hydrogen Evolution for Ultralow‐Voltage CO‐to‐Ethylene Electrolysis

Advanced Materials, EarlyView.
Gold‐stabilized copper suppresses hydroxide‐driven deactivation during anodic hydrogen evolution from furfural. Pairing this low‐potential anode with CO‐to‐ethylene electroreduction enables sub‐1 V operation at 400 mA cm−2, high single‐pass CO conversion, and co‐production of ethylene, furoic acid, and a separate hydrogen stream.
Sungjin Park, Hengzhou Liu, Heejong Shin, Hafiz Ghulam Abbas, Loann Bonnenfant, Ke Xie, Hyeon Seok Lee, Fatemeh Arabyarmohammadi, Jianan Erick Huang, Panos Papangelakis, Peiying Wang, Ali Shayesteh Zeraati, Jiheon Kim, Roham Dorakhan, David Sinton, Xiaopeng Liu, Wenzhen Li, Byoung‐hoon Lee, Edward H. Sargent   +18 more
wiley   +1 more source

Synthesis, characterisation, and catalytic application of a soluble molecular carrier of sodium hydride activated by a substituted 4-(dimethylamino)pyridine

Communications Chemistry
Recently main group compounds have stepped into the territory of precious transition metal compounds with respect to utility in the homogeneous catalysis of fundamentally important organic transformations.
Peter A. Macdonald, Alan R. Kennedy, Catherine E. Weetman, Stuart D. Robertson, Robert E. Mulvey   +4 more
doaj   +1 more source

Liquid Crystal Elastomer‐Based Haptic Pixel Arrays at Your Fingertips for Advanced Human–Machine Interfaces

Advanced Materials, EarlyView.
We mechanically program liquid crystal elastomer coatings as a stimuli‐responsive and digitally addressable platform for refreshable tactile displays; we validate the perceptual performance of our dynamic device matches conventional static tactile media.
Tom Bruining, Enjun Lin, Yu Zou, Meike Heldoorn, Pengrong Lyu, Samuël A. M. Weima, Astrid M. L. Kappers, Myrthe A. Plaisier, Satoshi Aya, Danqing Liu   +9 more
wiley   +1 more source

Review of Inorganic Separator Engineering for Next‐Generation Lithium–Sulfur Batteries: Compromise or Cornerstone?

Advanced Materials, EarlyView.
Inorganic compound‐modified separators transform lithium–sulfur batteries from passive polysulfide confinement to active reaction‐pathway regulation. A Practical Relevance Index (PRI)‐guided framework bridges interfacial chemistry of inorganic separators with practical constraints, establishing unified design principles for scalable, high‐energy ...
Yuting Qin, Tianyi Wang, Xingyu Wang, Kaifu Xu, Yuzhou Wang, Chengyin Wang, Bing Sun, Guoxiu Wang   +7 more
wiley   +1 more source

Conversion of organosolv pretreated hardwood biomass into 5-hydroxymethylfurfural (HMF) by combining enzymatic hydrolysis and isomerization with homogeneous catalysis. [PDF]

Biotechnol Biofuels, 2021
Dedes G, Karnaouri A, Marianou AA, Kalogiannis KG, Michailof CM, Lappas AA, Topakas E.   +6 more
europepmc   +1 more source

The role of METAMORPhos ligands in transition metal complex formation and catalysis [PDF]

, 2015
Chemists are challenged to develop homogeneous transition metal catalysts that are faster, more selective, cheaper, safer, robust and environmentally benign. This is generally approached by varying the ligands that are coordinated to the applied metal to
Oldenhof, S.
core   +11 more sources

Sub‐Nanometer Cobalt on Tungsten Titanium Carbide MXene (W2TiC2Tx): An Electrocatalyst for Highly Efficient and Stable Alkaline Hydrogen Evolution at Industrial‐Scale Current Density

Advanced Materials, EarlyView.
A novel W2TiC2Tx MXene prepared through a MAX‐phase route supports sub‐nanometer Co for highly efficient alkaline hydrogen evolution. Strong Co–W interfacial interactions optimize hydrogen adsorption and catalytic activity, enabling low overpotentials of 63 mV at 10 mA cm−2, small Tafel slope of 44.3 mV dec−1, and exceptional durability at industrially
Xiaopeng Liu, Fan Yang, Deep M. Patel, Mohammad Albloushi, Qiqi Mao, Shan Jiang, Christian J. Breckner, Connor W. Schroeder, Ruoyu Cui, Tao Ma, Dapeng Jing, Wenyu Huang, Jeffrey T. Miller, Wenzhen Li, Luke T. Roling, Yue Wu   +15 more
wiley   +1 more source

Coordination–driven encapsulation of transition metal complexes in molecular capsules and their application in hydroformylation and proton reduction catalysis [PDF]

, 2018
Traditional homogeneous catalysis applies catalysts based on organometallic complexes which are tuned by changing the metal and/or the ligands that are coordinated to it.
Nurttila, S.S.
core   +9 more sources