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Modular Homogeneous Chromophore–Catalyst Assemblies
Accounts of Chemical Research, 2016Photosynthetic reaction center (RC) proteins convert incident solar energy to chemical energy through a network of molecular cofactors which have been evolutionarily tuned to couple efficient light-harvesting, directional electron transfer, and long-lived charge separation with secondary reaction sequences. These molecular cofactors are embedded within
Karen L, Mulfort, Lisa M, Utschig
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Polymer Fibers as Carriers for Homogeneous Catalysts
Chemistry – A European Journal, 2007AbstractThis paper describes a polymer fiber‐based approach for the immobilization of homogeneous catalysts. The goal is to generate products that are free of catalysts which would be of great importance for the development of optoelectronic or pharmaceutical compounds.
Michael, Stasiak +3 more
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Journal of the American Chemical Society, 2005
A structurally characterized cationic chromium(III) alkyl featuring a bulky nacnac ligand catalyzes the polymerization of ethylene as well as the copolymerization of ethylene with alpha-olefins. This well-characterized homogeneous catalyst constitutes a structural as well as functional model of the widely used heterogeneous Phillips olefin ...
Leonard A, MacAdams +4 more
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A structurally characterized cationic chromium(III) alkyl featuring a bulky nacnac ligand catalyzes the polymerization of ethylene as well as the copolymerization of ethylene with alpha-olefins. This well-characterized homogeneous catalyst constitutes a structural as well as functional model of the widely used heterogeneous Phillips olefin ...
Leonard A, MacAdams +4 more
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Homogenizing Metal Oxide Catalysts
Journal of Macromolecular Science: Part A - Chemistry, 1981Abstract Metal oxide particles have been prepared which are “soluble” in hydrocarbon solvents. The reaction of either a metal (or its metal oxide) with water, mineral spirits, and a mixture of carboxylic acids can result in hydrocarbon-miscible metal oxide core particles of 20-1000A diameter sizes which are coated with a layer of hydrophobic ...
Charles U. Pittman +2 more
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“HETEROGENIZING” HOMOGENEOUS CATALYSTS
Catalysis Reviews, 1974Abstract For many years, it has been customary to classify catalysts as “homogeneous” or “heterogeneous.” The former commonly operate through the formation of “intermediate compounds,” and the latter, by adsorption of the reactants on the catalyst surface.
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Are Heterogeneous Catalysts Precursors to Homogeneous Catalysts?
Journal of the American Chemical Society, 2001I W, Davies +3 more
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Homogeneous and complex catalysts
Nature Synthesis, 2023Dongshuang Wu, Minna Cao
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Polyoxometalates as Homogeneous Oxidation Catalysts
2012Anstract
CARRARO, MAURO +7 more
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Decomposition pathways of homogeneous catalysts
Applied Catalysis A: General, 2001Homogeneous catalysts can decompose in a variety of ways: metal deposition, ligand decomposition, reaction with impurities, dimer formation, and reaction of the metal center with the ligand. Sometimes these side reactions lead to temporary deactivation only and the catalyst activity can be restored. Without attempting to be complete, I have collected a
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