Results 111 to 120 of about 54,472 (289)

Sequential Homo‐ and Hetero‐Coupling of Isocyanide and Carbon Monoxide Mediated by Acyclic Imino(silyl)Silylene

Angewandte Chemie, EarlyView.
We demonstrate the sequential reactions between an imino(hypersilyl)silylene and aryl isocyanide or carbon monoxide as a molecular‐level model of the Fischer–Tropsch process, providing systematic and detailed insight into C–C bond formation during the homologation of C1 building blocks.
Huaiyuan Zhu, Arseni Kostenko, Xufang Liu, Shigeyoshi Inoue   +3 more
wiley   +2 more sources

Validating large-scale quantum machine learning: efficient simulation of quantum support vector machines using tensor networks

Machine Learning: Science and Technology
We present an efficient tensor-network-based approach for simulating large-scale quantum circuits exemplified by quantum support vector machines (QSVMs).
Kuan-Cheng Chen, Tai-Yue Li, Yun-Yuan Wang, Simon See, Chun-Chieh Wang, Robert Wille, Nan-Yow Chen, An-Cheng Yang, Chun-Yu Lin   +8 more
doaj   +1 more source

Organophosphide: Eine neue Klasse der Luminophorliganden für Kupfer(I)‐Carben‐basierte TADF‐Emitter und Photokatalysatoren

Angewandte Chemie, EarlyView.
Der Einsatz von Dimesitylphosphid als höheres Homolog der etablierten Amidoliganden für Charge‐Transfer‐Kupfer(I)‐Komplexe führt zu einer Rotverschiebung der Emission um 3645 cm–1 in den rot‐orangen Spektralbereich im Festkörper sowie in den NIR‐Bereich in Lösung. Die thermisch‐aktivierte verzögerte Fluoreszenz weist hohe Dissymmetriefaktoren von glum =
Paul C. Ruer, Julian J. Holstein, Andreas Steffen   +2 more
wiley   +1 more source

Flow diversion for unruptured MCA bifurcation aneurysms: comparison of p64 classic, p64 MW HPC, and p48 MW HPC flow diverter stents

Frontiers in Neurology
BackgroundMCA bifurcation aneurysms pose treatment challenges because of the complex hemodynamics at the bifurcation and the risk of rupture. FDS implantation has been controversial and there are only limited reports. Therefore, the aim of this study was
V. Hellstern, N. Brenner, A. Cimpoca, P. Albina Palmarola, E. Henkes, C. Wendl, H. Bäzner, O. Ganslandt, H. Henkes, H. Henkes   +9 more
doaj   +1 more source

Der Nicht‐Adiabatische Charakter von Substituenteneffekten in Azobenzol

Angewandte Chemie, EarlyView.
Vereinheitlichung Nicht‐Adiabatischen Schaltens: die thermische Z→E Isomerisierung von para‐substitutierten Azobenzolen verläuft über einen einzelnen Reaktionsweg mit nicht‐adiabatischem Charakter. Anstatt eines mechanistischen Wechsels spiegelt der bekannte V‐förmige Hammett Graph ein Artefakt des σp Parameters, zeigt so die Grenzen von DFT auf und ...
Jacob Jan van der Wal, Roman Yu. Peshkov, Jorn D. Steen, Nadja A. Simeth, Stefano Crespi   +4 more
wiley   +1 more source

Evaluation of starch granules based on hydroxypropylcellulose as a substitute for excipient lactose

Journal of Pharmaceutical Health Care and Sciences
Background The improvement in flowability and adhesion of starch powder (SP) is essential for using starch as an excipient for lactose intolerant patients.
Tomohiro Yoshikawa, Hiroyo Okamoto, Kenta Takeuchi, Atsushi Hirata, Hiroko Otake, Noriaki Nagai   +5 more
doaj   +1 more source

Scalable3-BO: Big Data Meets HPC - A Scalable Asynchronous Parallel High-Dimensional Bayesian Optimization Framework on Supercomputers [PDF]

, 2021
Anh Tran
openalex   +1 more source

Towards Cloud-based Asynchronous Elasticity for Iterative HPC Applications [PDF]

, 2015
Rodrigo da Rosa Righi, Vinicius Facco Rodrigues, Cristiano André da Costa, Diego Kreutz, Hans-Ulrich Heiß   +4 more
openalex   +1 more source

Organophosphides: A New Class of Luminophore Ligands for Copper(I) Carbene Based TADF Emitters and Photocatalysts

Angewandte Chemie International Edition, EarlyView.
Dimesitylphosphide as a heavier congener of established amide ligands for charge‐transfer copper(I) complexes leads to bathochromic shift of the emission by up to 3645 cm−1 into the orange‐red (solid, polymer films) and even NIR (solution). The thermally activated delayed fluorescence exhibits high dissymmetry factors of glum = 10−2 in polystyrene.
Paul C. Ruer, Julian J. Holstein, Andreas Steffen   +2 more
wiley   +1 more source

A Scalable, Distributed Monitoring Framework for HPC Clusters Using Redfish-Nagios Integration [PDF]

, 2023
Ghanzanfar Ali, Jon Hass, A. Sill, Elham Hojati, Tommy Dang, Yong Chen   +5 more
openalex   +1 more source