Results 221 to 230 of about 253,481 (293)

Rational Optimization of Self‐Reporting Alcohol‐Oxidizing RhIII$^{\mathrm{III}}$ Complexes

European Journal of Inorganic Chemistry, EarlyView.
A series of four different [(NN)Rh(Cp*)X]n+$^{\mathrm{n+}}$ complexes (NN = chelating α$\alpha$‐diimine ligand, Cp* = pentamethylcyclopentadienyl, X = Cl, solvent) are reported which all do possess a colorimetric self‐reporting property upon alcohol oxidation formation of the Rh(I) state. Analysis of alcohol oxidation rates
Luca Hefty, Giada Caniglia, Muhammed Abdel‐Hamied, Alexander K. Mengele, Christine Kranz, Sven Rau   +5 more
wiley   +1 more source

Masked Silylenes: Controlled Generation and Reactivity Under Thermal and Equilibrium Conditions

European Journal of Inorganic Chemistry, EarlyView.
This Review provides an overview of masked silylenes as bench‐stable precursors that release silylenes (R2Si:) under thermal activation or reversible equilibria. Precursor preparation, generation pathways, and characteristic reactivity are summarized, including trapping chemistry, reversible interconversions, insertion‐type processes, and small ...
Kei Ota, Kanata Miyahara, Norio Nakata
wiley   +1 more source

A Divergent Asymmetric Total Synthesis of Coprophilin and Four Trichodermic Acids via a [1,5]-Hydride Shift-Aldol Cascade. [PDF]

J Am Chem Soc
Smith E, Jenkins TC, Yeung CS, Donohoe TJ.   +3 more
europepmc   +1 more source

From Phosphinimines to Four‐Membered SiCPN Cations: Insights Into N–Si Bonding and Ring Strain

European Journal of Inorganic Chemistry, EarlyView.
Sterically tuned N‐silyl phosphinimines enable four‐membered SiCPN cations. Hydride abstraction yields cyclic cations for Me and iPr substituents at silicon, while tBu gives a protonated intermediate. Multinuclear NMR spectroscopy, X‐ray crystallography, thermochemical density functional theory investigations, and natural bond orbital analyses reveal ...
Alexander Falk, Jonathan O. Bauer
wiley   +1 more source

Active bridging hydride species in ZnO nanorods originated from hydroxyl and oxygen vacancy. [PDF]

Nat Commun
Song B, Feng Z, Wu XP, Gu Y, Xie L, Zhu Q, Peng L.   +6 more
europepmc   +1 more source

Ligand‐Level Chemical Activation: Coordination with Benefits

European Journal of Inorganic Chemistry, EarlyView.
While often perceived as a liability, ligand‐based reactivity in carefully designed settings becomes a powerful synthetic tool. The key to streamlined processes overriding classical ionic reactivity is the selective electron redistribution induced by metal coordination. This enables storage of electrons and protons or incorporation of functional groups
Oscar Charpentier, Agnideep Das, Marine Desage‐El Murr   +2 more
wiley   +1 more source

A heterometallic σ-silane adduct from cooperative reactivity of an iron-aluminium complex.

Chem Commun (Camb)
Stadler B, Crimmin MR.
europepmc   +1 more source

Tailoring hydrogenation, thermodynamic properties and oxidation resistance of TiFe alloy by only regulating the stoichiometric ratio of Ti and Fe elements. [PDF]

RSC Adv
Xia S, Wu G, Huang D, Ma G, Cai H, Jiang J, Zhou Q, Yan X, Lv P.   +8 more
europepmc   +1 more source

Amphoteric Behavior of Hydrogen in Lanthanum Oxyhydrides: Correlation with Electrochemical Properties. [PDF]

J Am Chem Soc
Yamasaki T, Fukui K, Iimura S, Tsuda S, Mizoguchi H, Omata T, Hosono H.   +6 more
europepmc   +1 more source

Mediator-Enabled Co-Catalyzed <i>Z</i>‑Selective Semihydrogenation via Hydride-Free Multisite Proton-Coupled Electron Transfer. [PDF]

ACS Catal
Parnitzke B, Lalisse R, Gerhardt E, Maity T, Liu Y, Xuan Z, Gutierrez O, Derosa J.   +7 more
europepmc   +1 more source