Results 231 to 240 of about 576,528 (285)

Rapid and Stereoselective Ring‐Opening Polymerization of rac‐Lactide Enabled by a Chiral Cyclopropenimine–Thiourea Catalyst

open access: yesAngewandte Chemie, EarlyView.
Chiral cyclopropenimine–thiourea organocatalysts enabled both high reactivity and precise stereocontrol in the ring‐opening polymerization of rac‐lactide. The bifunctional system exhibited a TOF up to 1,710 h−1 with Pm = 0.90 at 25°C, and achieved Pm = 0.99 at −78°C while maintaining a TOF of 16.3 h−1.
Sumin Lee   +8 more
wiley   +1 more source

One‐Dimensional Polycyclic Aromatic Hydrocarbons Incorporating Multiple Dithiafulvene Units—Novel Multi‐Redox and Electrochromic Systems

open access: yesAngewandte Chemie, EarlyView.
Planar polycyclic aromatic hydrocarbons (PAHs) incorporating three or four dithiafulvene (DTF) units were synthesized via Horner–Wadsworth–Emmons reactions to create large π‐conjugated redox‐active frameworks. These molecules display strong intermolecular associations and distinct odd–even redox behavior, enabling formation of mixed‐valence and radical‐
Cecilie Rindom   +3 more
wiley   +1 more source

From Methane to Nanodiamond Precursors in Water: Superacid-like Condensation Pathways Under Extreme Conditions. [PDF]

open access: yesAngew Chem Int Ed Engl
Thévenet T   +6 more
europepmc   +1 more source

Regiodivergent C3 and C4 Amination of Quinolines via Radical and Ionic Pathways

open access: yesAngewandte Chemie, EarlyView.
A regiodivergent strategy converts a single N‐aminoquinolinium precursor into either C3‐ or C4‐aminated quinolines. Nucleophile‐induced dearomatization diverges into light‐driven N‐centered radical capture (C3) or base‐promoted SNAr (C4), enabling rapid assembly of aminoquinoline libraries and late‐stage diversification.
Ye‐Eun Kim   +3 more
wiley   +1 more source

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