Results 231 to 240 of about 148,309 (314)

Anionic T‐Shaped Platinum(0) Pincer Complexes and Platinum(I) Intermediates in Radical Reactions With Alkyl Halides

open access: yesAngewandte Chemie, EarlyView.
Two anionic, T‐shaped, d10 platinum(0) complexes containing a PNP pincer ligand have been isolated and characterized. These complexes react with aliphatic C‐Br bonds under formation of a platinum(II) bromide and an alkyl complex, as well as the homocoupled hydrocarbons.
Vincenz J. Kohler   +6 more
wiley   +1 more source

Development of Sub‐50 nm Core–Shell Silica Nanoparticles With Controlled In Vivo Behavior for 19F Magnetic Resonance Imaging

open access: yesAngewandte Chemie, EarlyView.
Ultrasmall PFCE‐loaded silica nanoparticles synthesized through a one‐pot double‐emulsion synthesis method, where rapid silica shell formation kinetically fixes droplet size. The resulting s‐FLAME nanoparticles enable strong 19F MRI signals with enhanced hepatic clearance rate and tumor‐accumulation performance. ABSTRACT 19F magnetic resonance imaging (
Yue Wu   +2 more
wiley   +1 more source

Crosslinking of Linear Polyimines Into Aminal‐Linked Porous Organic Polymers for C2 Hydrocarbon/Methane Separation

open access: yesAngewandte Chemie, EarlyView.
Crosslinking of linear polyimines with aromatic diamines via nucleophilic addition converts nonporous polyimine precursors into aminal‐linked porous networks, offering a new strategy for synthesizing porous organic polymers. The resulting materials exhibit high C2 hydrocarbon adsorption capacity, excellent selectivity over CH4, and durable cyclic ...
Xuejie Li   +4 more
wiley   +1 more source

Taxonomic Profiling of Bacterial Communities Associated with Metals in the Tar Mats and Cyanobacterial Mats of the Qatar Coast, Arabian Gulf. [PDF]

open access: yesMicrob Ecol
Haseeba KP   +7 more
europepmc   +1 more source

π‐Radical Cascades to Peri‐Fused Triangulene Dimers

open access: yesAngewandte Chemie, EarlyView.
We demonstrate the potential of open‐shell molecular graphene fragments as synthons for constructing graphene nanostructures via π‐radical cascades. By identifying monoradical intermediates as key selectivity‐determining species and tuning steric effects in a triangulene precursor, we show that reactivity in a formally diradical system can be ...
Paula L. Widmer   +10 more
wiley   +1 more source

Iterative Synthesis of Pyrene–Coronene Molecular Graphene Nanoribbons

open access: yesAngewandte Chemie, EarlyView.
An iterative approach delivers a new family of undoped, cove‐edged graphene nanoribbons with lengths up to 9.1 nm that exhibit both molar absorptivity and fluorescence brightness values on the order of 105 M−1 cm−1 and an intrinsic charge‐carrier mobility of 475 ± 32 cm2 V−1 s−1.
Miguel A. Medel   +6 more
wiley   +1 more source

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