Results 231 to 240 of about 533,861 (287)

Matrimid‐Derived Asymmetric Carbon Molecular Sieve Hollow Fibers With Engineered Ultramicropores for Precise Helium Separation

open access: yesAngewandte Chemie, EarlyView.
Matrimid‐derived asymmetric carbon molecular sieve (CMS) hollow fibers enable ultraselective helium/methane (He/CH4) separation. Post‐pyrolysis hyperaging selectively tightens larger ultramicropores, enhancing He/CH4 discrimination while maintaining high He permeance.
Zhongyun Liu   +3 more
wiley   +1 more source

Ion‐Lock Storage With Multi‐Logic Circuitry Gated by Polar–Dipolar Interactions in Poly(Ionic Liquids)

open access: yesAngewandte Chemie, EarlyView.
Precise building block design of poly(ionic liquids) creates an opportunity to achieve ionic conductivity, energy storage, and multi‐value logic in one material while eliminating elaborate fabrication processes. ABSTRACT In these studies, we developed a new generation of polymeric materials capable of electrical energy storage and forming higher‐than ...
Sourav Biswas   +3 more
wiley   +1 more source

Functionalization of Saturated and Unsaturated Hydrocarbons with Electrophilic Anions [B<sub>12</sub>X<sub>11</sub>]<sup>-</sup> (X = Br, I) in the Gas Phase and at Interfaces. [PDF]

open access: yesJ Phys Chem A
Rohdenburg M   +9 more
europepmc   +1 more source

Chiral Heptagon‐Embedded Double [6]Helicenes via Scholl Reaction

open access: yesAngewandte Chemie, EarlyView.
One bond makes the difference–two chiral and twisted polycyclic aromatic hydrocarbons (PAHs) show different emission behavior. The more flexible one (top) shows a double emission with one having a large anti‐Stokes shift. The two peaks are assigned to different conformers of one and the same compound.
Dan Wang   +6 more
wiley   +1 more source

NiH‐Catalyzed Enantioconvergent α‐Alkenylation of Carbonyl Compounds via Markovnikov Alkyne Hydronickellation

open access: yesAngewandte Chemie, EarlyView.
A NiH‐catalyzed α‐alkenylation via Markovnikov hydronickellation of alkynes enables convenient access to α‐chrial β‐methylene carbonyl frameworks that are prevalent in biorelevant molecules. High regio‐ and enantioselectivities have been achieved with excellent functional group tolerance and applicability toward complex structures. The β‐methylene unit
Hyeontaek Nam   +3 more
wiley   +1 more source

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