Results 91 to 100 of about 9,719 (242)

Nanostructured Deep Eutectic Systems in Healthcare: From Bioactive Solvents to Intelligent Biointerfaces, Wearables, and AI‐Driven Design

open access: yesAdvanced NanoBiomed Research, EarlyView.
Beyond the green solvent paradigm, this review redefines Deep Eutectic Systems (DES) as programmable supramolecular nanoassemblies. We survey their biomedical convergence: stabilizing thermolabile mRNA to enable cold chain‐free logistics, reshaping transdermal microneedle delivery, enabling long‐term wearables via eutectogels, and utilizing Generative ...
Jeesu Moon, Min Seo Kim, Jae‐Seung Lee
wiley   +1 more source

Hyperpolarization of Pyridine 15N‐Oxide Molecular Probes Enabled by Parahydrogen

open access: yesAngewandte Chemie, EarlyView.
Pyridine 15N‐oxides are introduced as motifs for hyperpolarization studies and biochemical applications are demonstrated. ABSTRACT Magnetic resonance (MR) is a powerful non‐invasive technique for probing structural, functional, and metabolic processes with high spatial and temporal resolution.
Ruhuai Mei   +8 more
wiley   +2 more sources

Key Drivers of Activity and Selectivity in Cu‐Based Catalysts for Methanol Synthesis From CO2: Insights From Atomically Dispersed Promoters

open access: yesAngewandte Chemie, EarlyView.
Mechanistic studies on model Cu─M/SiO2 catalysts (M = Zn, Ga, and In) reveal that promoters enable a formate spillover pathway from Cu to Mn+ (n = 2 or 3) sites. The promoter's electronic effect on formate bond strengths serves as a quantitative descriptor for activity and selectivity, balancing spillover dynamics with intermediate stabilization to ...
Nat Phongprueksathat   +6 more
wiley   +2 more sources

Enriched and Sustained Oxygen Vacancies in Amorphous NiWOx Enhance and Stabilize Urea Electrooxidation

open access: yesAngewandte Chemie, EarlyView.
We propose an “amorphous oxygen mechanism (AOM)” for urea electrooxidation on amorphous NiWOx with tunable Ov, which achieves robust UOR activity and stability simultaneously. The “amorphous oxygen” in NiWOx prefers to escape during the UOR, in situ generating and stabilizing Ov, which thermodynamically promotes the reaction.
Yinuo Wang   +9 more
wiley   +2 more sources

Modulating Local Coordination in Single‐Atom Catalysts: From Fundamental Concepts to Emerging Breakthroughs in Electrocatalysis

open access: yesAngewandte Chemie, EarlyView.
This review summarizes atomic‐level design strategies for single‐atom catalysts, emphasizing modulation of the local coordination environment, active‐site geometry, and metal‐support interactions to optimize catalytic activity and stability in electrocatalytic energy conversion applications.
Ashwani Kumar, Harun Tüysüz
wiley   +2 more sources

Estimation of Soil Evaporation in Apple Orchards Based on Hydrogen and Oxygen Isotopes

open access: yesAgronomy
Accurate estimation of soil evaporation and plant transpiration is crucial for the scientific and effective management of water resources in apple orchards. Using apple orchards of varying ages as research subjects, the Craig–Gordon model was employed to
Jialiang Huang   +8 more
doaj   +1 more source

Coupled Fe3O4‐Cluster Precipitates and Single Fe‐Atom Catalysts Can Boost Oxygen Reduction via Concomitantly Accelerated Water Dissociation

open access: yesAngewandte Chemie, EarlyView.
Fe3O4 clusters can be precipitated onto Fe–N–C SACs through a residual‐oxygen‐assisted precipitation approach. Compelling evidence, including operando spectroscopy and ab initio calculations, suggests that Fe3O4‐cluster precipitates not only induce asymmetric electronic structures of Fe‐N4 active center to optimize the OH* adsorption, but also ...
Cheng‐Kai Du   +10 more
wiley   +2 more sources

Hydrogen and Oxygen Isotopes in Hydrology

open access: yesHydrogen and Oxygen Isotopes in Hydrology
identifier:oai:t2r2.star.titech.ac.jp ...
openaire  

Tailoring High‐Valent Iron‐Oxo Species Redox via Extended π‐Fe3d–O2p Orbital Overlapping Toward Chemical‐Efficient Water Purification

open access: yesAngewandte Chemie, EarlyView.
We address the long‐standing challenge of reactivity–selectivity trade‐off by precisely tuning the redox properties of Fe(IV), rather than simply accelerating its formation, to enable chemically efficient and low‐emission water treatment. ABSTRACT High‐valent iron oxo species (Fe(IV)) are attractive for wastewater treatment because of their high ...
Hongyu Zhou   +9 more
wiley   +2 more sources

Preparation and Certification of Reference Materials for Hydrogen and Oxygen Isotopes in Water

open access: yesYankuang ceshi, 2013
Certified reference materials of water for stable hydrogen and oxygen isotopes were developed and have been used for more than 30 years. However, they no longer meet the requirements for newly developed technologies. New reference materials of water have
ZHANG Lin   +3 more
doaj  

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