Results 151 to 160 of about 13,098 (230)

Indium Clusters With 6s2 Lone‐Pair Effect as Excitonic Electron Reservoirs for Direct 2e− Photocatalytic H2O2 Photosynthesis

open access: yesAngewandte Chemie, EarlyView.
This study demonstrates that indium clusters with 6s2 lone‐pair effect anchored on carbon nitride act as excitonic electron reservoirs to boost charge separation and O2 activation for highly selective direct 2e− oxygen reduction. This work establishes cluster‐mediated electron reservoir engineering as a general strategy for enhancing selective ...
Shijie Xie   +7 more
wiley   +2 more sources

Light hydrogen isotopes in terrestrial core. [PDF]

open access: yesSci Adv
Zhang Y, Wang W, Deng Z, Wu Z, Chen B.
europepmc   +1 more source

Pt‐Mediated Co‐Adsorption of Hydroxyl and Nitrogen‐Heterocyclic Species Over Cu/CuO Heterostructure Enhances Coupled Azotriazole Electrosynthesis and Dual‐Electrode Hydrogen Production

open access: yesAngewandte Chemie, EarlyView.
Pt@Cu/CuO heterostructures were designed for electrochemical N─N coupling of 3,5‐diamino‐1H‐1,2,4‐triazole. Mechanism investigation revealed that the Pt sites mediated co‐adsorption of substrates and hydroxyl on Cu/CuO sites. The elaborate Pt@Cu/CuO achieved an ultralow working potential of 0.832 VRHE with a high FE of 95%. A long‐term stability of 600
Jiachen Li   +11 more
wiley   +2 more sources

Elucidating Photo‐Kinetic Control in Photothermal Reverse Water‐Gas Shift Reaction

open access: yesAngewandte Chemie, EarlyView.
Light directly regulates the rate‐determining step (RDS) in photothermal catalysis. In a Mars–van Krevelen (MvK)‐type reverse water‐gas shift (RWGS) reaction over In‐doped MoO2, light shifts the RDS from the H2‐related reduction half‐reaction to the CO2‐related oxidation half‐reaction, enhancing catalytic activity and lowering the apparent activation ...
Junchuan Sun   +13 more
wiley   +2 more sources

Water-Dispersible Ruthenium Nanocatalyst for Carbonyl Reduction With D<sub>2</sub> or T<sub>2</sub> in Aqueous Media. [PDF]

open access: yesAngew Chem Int Ed Engl
Martinelli E   +6 more
europepmc   +1 more source

Engineering Atomically Precise Cu4I4 Nanoclusters With Integrated Adsorption and Hydrogenation Functions for Efficient Photocatalytic Nitrate‐to‐Ammonia Conversion

open access: yesAngewandte Chemie, EarlyView.
Efficient photocatalytic nitrate‐to‐ammonia conversion is achieved over an atomically precise Cu4I4 motif through dual‐site cooperation. Lewis‐acidic Cu centers promote nitrate adsorption and activation, while adjacent I sites facilitate active hydrogen generation for stepwise hydrogenation.
Wanting Zhang   +13 more
wiley   +2 more sources

Intra-annual transfer of hydrogen and oxygen isotopic signals from water and sugar precursors to tree rings: Processes and mechanisms. [PDF]

open access: yesNew Phytol
Diao H   +10 more
europepmc   +1 more source

Global Soil Water Stable Isotope Dataset. [PDF]

open access: yesSci Data
Yang J   +17 more
europepmc   +1 more source

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