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Intercepting Hydrogen Evolution with Hydrogen-Atom Transfer: Electron-Initiated Hydrofunctionalization of Alkenes.

Journal of the American Chemical Society, 2022
Hydrogen-atom transfer mediated by earth-abundant transition-metal hydrides (M-Hs) has emerged as a powerful tool in organic synthesis. Current methods to generate M-Hs most frequently rely on oxidatively initiated hydride transfer.
Xiangyu Wu   +7 more
semanticscholar   +1 more source

Hydroalkylation of Unactivated Olefins via Visible-Light-Driven Dual Hydrogen Atom Transfer Catalysis.

Journal of the American Chemical Society, 2021
Radical hydroalkylation of olefins enabled by hydrogen atom transfer (HAT) catalysis represents a straightforward means to access C(sp3)-rich molecules from abundant feedstock chemicals without the need for prefunctionalization.
Guangyu Lei   +4 more
semanticscholar   +1 more source

Direct C–H Arylation of Aldehydes by Merging Photocatalyzed Hydrogen Atom Transfer with Palladium Catalysis

ACS Catalysis, 2020
Herein, we report that merging palladium catalysis with hydrogen atom transfer (HAT) photocatalysis enabled direct arylations and alkenylations of aldehyde C–H bonds, facilitating visible light-cat...
Lu Wang   +9 more
semanticscholar   +1 more source

Hydrogenation of Alkenes via Cooperative Hydrogen Atom Transfer.

Journal of the American Chemical Society, 2020
Radical hydrogenation via hydrogen atom transfer (HAT) to alkenes is an increasingly important transformation for the formation of thermodynamic alkane isomers.
Padmanabha V. Kattamuri, Julian G. West
semanticscholar   +1 more source

Photocatalytic hydrogen atom transfer: the philosopher's stone for late-stage functionalization?

, 2020
An overview about the potentialities of photocatalytic Hydrogen Atom Transfer (HAT) for the Late-Stage Functionalization (LSF) of complex molecules is offered.
Luca Capaldo   +2 more
semanticscholar   +1 more source

The Atomic Hydrogen Maser [PDF]

open access: possibleIRE Transactions on Instrumentation, 1961
The atomic hydrogen maser is described. In this device hydrogen atoms in the upper hyperfine state are focused onto the entrance aperture of a Teflon coated quartz bulb in which the atoms are stored for about a second. This bulb is surrounded by a cylindrical radiofrequency cavity; When the cavity is tuned to the hyperfine frequency of atomic hydrogen,
openaire   +3 more sources

Metal-Free Electrocatalyst for Water Oxidation Initiated by Hydrogen Atom Transfer

, 2020
Direct activation of O–H bond in water via hydrogen atom transfer (HAT) reactions is a challenge because of its high bond dissociation energy.
Han Li, Fei Xie, Ming‐Tian Zhang
semanticscholar   +1 more source

The Hydrogen Atom [PDF]

open access: possible, 2010
Based on the discussions in Chap. 4 we will now apply the quantum mechanical treatment to the simplest atom, the H atom, which consists of one proton and one electron moving in the spherical symmetric Coulomb potential of the proton. These one-electron systems, such as the hydrogen atom and the ions He+, Li++, Be+++, etc., are the only real systems for
openaire   +1 more source

On a hydrogen atom [PDF]

open access: possibleLithuanian Mathematical Journal, 2007
We represent the deterministic substitute of the Schrodinger equation for a hydrogen atom in precise accordance with the Bohm-de Broglie interpretation of quantum mechanics. To construct a mathematical model, the Weierstrass theorem and limit cycles are used. This method can be applied to many-electron atoms.
openaire   +1 more source

The Dual Role of Benzophenone in Visible-Light/Nickel Photoredox-Catalyzed C-H Arylations: Hydrogen-Atom Transfer and Energy Transfer.

Angewandte Chemie, 2019
A dual catalytic protocol for the direct arylation of non-activated C(sp3 )-H bonds has been developed. Upon photochemical excitation, the excited triplet state of a diaryl ketone photosensitizer abstracts a hydrogen atom from an aliphatic C-H bond. This
Abhishek Dewanji   +2 more
semanticscholar   +1 more source

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