Results 271 to 280 of about 611,030 (339)

Fluoride‐Free Molten Salt Hydrate‐Assisted Synthesis of MXene in Air Down to 150 °C

Advanced Functional Materials, EarlyView.
A novel low‐temperature shielded salt (LSS) approach enables the synthesis of MXenes in air at temperatures as low as 150 °C using MgCl2·6H2O/LiCl. This method demonstrates successful etching of challenging MXenes like Cr2CTx and Nb2CTx through the synergistic effects of Li+ ions and salt hydrate phase changes, while eliminating the need for inert ...
Sin‐Yi Pang, Weng Fu Io, Lok‐Wing Wong, Xinyue Lao, Qianqian Bai, Kam Lin Chan, Jiong Zhao, Jianhua Hao   +7 more
wiley   +1 more source

Visible-light-driven net-1,2-hydrogen atom transfer of amidyl radicals to access β-amido ketone derivatives. [PDF]

Chem Sci
Jiang Y, Li H, Tang H, Zhang Q, Yang H, Pan Y, Zou C, Zhang H, Walsh PJ, Yang X.   +9 more
europepmc   +1 more source

Differential Compartmentalization of Enzymatic Reactions for Lactate Signaling Across Protocells

Advanced Functional Materials, EarlyView.
Two populations of protocells consisting of giant unilamellar vesicles containing active species and distinct artificial organelles are competent of collective behavior by mimicking production, intercellular communication, and detection of the bioinspired signal molecule lactate. Enzymatic cascade reactions within artificial organelles demonstrate that
Arianna Balestri, Xinan Huang, Emanuel Lörtscher, Cora‐Ann Schoenenberger, Cornelia G. Palivan   +4 more
wiley   +1 more source

C(sp³)-H sulfinylation of light hydrocarbons with sulfur dioxide via hydrogen atom transfer photocatalysis in flow. [PDF]

Nat Commun
Nagornîi D, Raymenants F, Kaplaneris N, Noël T.   +3 more
europepmc   +1 more source

Harnessing Interfacial Cl− Ions for Concurrent Formate Production at Industrial Level via CO2 Reduction and Methanol Oxidation

Advanced Functional Materials, EarlyView.
The replacement of the anodic OER in CO2RR with energy‐saving methanol oxidation reaction and the creation of a favorable microenvironment through interfacial Cl− ions enable concurrent formate production at industrial‐level current densities. Abstract The efficient electrocatalytic conversion of CO2 to formate is often impeded by the high energy ...
Yiqun Chen, Yan Zhang, Zhen Li, Biao Feng, Mengting Li, Qiang Wu, Zheng Hu, Lawrence Yoon Suk Lee   +7 more
wiley   +1 more source

Site-selective α-C(sp³)-H arylation of dialkylamines via hydrogen atom transfer catalysis-enabled radical aryl migration. [PDF]

Nat Commun
Xu J, Li R, Ma Y, Zhu J, Shen C, Jiang H.   +5 more
europepmc   +1 more source

Enhancing Direct Solar Water Splitting via ALD of Multifunctional TiO2/Pt Nanoparticle Coatings With Engineered Interfaces to GaAs/GaInP Tandem Cells

Advanced Functional Materials, EarlyView.
Multifunctional atomic layer deposited coatings and interface treatments enhance direct solar water splitting on GaAs/GaInP tandem cells. Optimized TiO2/Pt nanoparticle bilayers ensure durability and catalytic efficiency with minimal optical losses, while H2 plasma pretreatments maximize photovoltage and interfacial charge extraction.
Tim F. Rieth, Verena Streibel, Oliver Bienek, Sergej Levashov, Johannes Dittloff, Kristof Möller, Johanna Eichhorn, Matthias M. May, Ian D. Sharp   +8 more
wiley   +1 more source

Thermodynamic H-Abstraction Abilities of Nitrogen Centered Radical Cations as Potential Hydrogen Atom Transfer Catalysts in Y-H Bond Functionalization. [PDF]

ACS Omega
Zhao X, Hou YL, Qian BC, Shen GB.
europepmc   +1 more source

Substrate Engineering for Durable Omniphobic Liquid‐Like Surfaces

Advanced Functional Materials, EarlyView.
The significant yet less investigated role of substrates in determining the liquid‐repellency and mechanical durability of liquid‐like surfaces (LLSs) is explored. Thick and crack‐free sol–gel silica intermediary layers are developed that can smoothen substrate asperity roughness even at the micron scale, enabling omniphobic polydimethylsiloxane‐based ...
Tao Wen, Isaac J. Gresham, Rafaela Aguiar, Sudip K. Lahiri, Patrick C. Lee, Chiara Neto, Kevin Golovin   +6 more
wiley   +1 more source

Predicting hydrogen atom transfer energy barriers using Gaussian process regression.

Digit Discov
Ulanov E, Qadir GA, Riedmiller K, Friederich P, Gräter F.   +4 more
europepmc   +1 more source