Hydrogen atom abstraction by a high spin [FeIII=S] complex. [PDF]
Chem, 2023 Iron sulfur clusters are critical to a plethora of biological processes; however, little is known about the elementary unit of these clusters, namely the [Fe=S]n+ fragment. Here, we report the synthesis and characterization of a terminal iron sulfido complex.
Valdez-Moreira JA +6 more
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Visible Light-Mediated Dearomative Hydrogen Atom Abstraction/ Cyclization Cascade of Indoles. [PDF]
Angew Chem Int Ed Engl, 2022 Xiong Y, Großkopf J, Jandl C, Bach T.
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Beyond the classical thermodynamic contributions to hydrogen atom abstraction reactivity. [PDF]
Proc Natl Acad Sci U S A, 2018 Significance Hydrogen atom abstraction reactivity is a key property of many important biological and synthetic compounds that depends on their proton-coupled reduction potentials. These potentials quantify the ability of species to acquire an electron and proton pair.
Bím D +3 more
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New Catalytic Radical Process Involving 1,4-Hydrogen Atom Abstraction: Asymmetric Construction of Cyclobutanones. [PDF]
J Am Chem Soc, 2021 Xie J +5 more
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Mechanisms for Hydrogen-Atom Abstraction by Mononuclear Copper(III) Cores: Hydrogen-Atom Transfer or Concerted Proton-Coupled Electron Transfer? [PDF]
J Am Chem Soc, 2019 Mandal M +5 more
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Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis. [PDF]
Angew Chem Int Ed Engl, 2018 Twilton J +5 more
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DFT Investigation of Hydrogen Atom Abstraction from NHC-Boranes by Methyl, Ethyl and Cyanomethyl Radicals-Composition and Correlation Analysis of Kinetic Barriers. [PDF]
Molecules, 2020 Qu HJ, Yuan L, Jia CX, Yu HT, Xu H.
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Reaction of an iron(IV) nitrido complex with cyclohexadienes: cycloaddition and hydrogen-atom abstraction. [PDF]
Inorg Chem, 2014 Lee WT +6 more
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Selective Hydrogen Atom Abstraction by Hydrogen Atoms in Photolysis and Radiolysis of Alkane Mixtures at 77 K [PDF]
Bulletin of the Chemical Society of Japan, 1976 Abstract A selective hydrogen atom abstraction reaction by H atoms, which are produced at 77K by radiolysis of alkane or photolysis of hydrogen halides, has been found in isobutane, 2,2,3,3-tetramethylbutane (TMB), and cyclopropane matrices as well as in the neopentane matrix. The selective hydrogen atom abstraction reaction is caused by
Tetsuo Miyazaki +3 more
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DFT investigation of hydrogen atom-abstraction reactions of NHC-boranes by various carbon-centered radicals: barriers and correlation analyses. [PDF]
RSC Adv, 2020 Qu HJ, Yuan L, Jia CX, Yu HT, Xu H.
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